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- 저자 : Huan-Ping Chao (검색결과 3 건)
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Huan-Ping Chao,Chung-Cheng Chang,Aileen Nieva 한국공업화학회 2014 Journal of Industrial and Engineering Chemistry Vol.20 No.5
This study used three types of agricultural waste, Citrus maxima peel, passion fruit shell, and sugarcane bagasse, to produce biosorbents for copper(II), cadmium(II), nickel(II), and lead(II) metal ion removal in a fixed-bed column. The biosorbent properties were characterized using scanning electron microscopy, zeta potential analysis, Fourier transform infrared spectroscopy, and cation exchange capacity. The adsorption capacities were determined using the Thomas model for various pH values and flow rates. The results indicated that biosorbents possess carboxylic acid groups, which function as exchangeable cation and complexation sites for removing heavy metals. The biosorbents exhibited great adsorption capacity.
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Hai Nguyen Tran,Sheng-Jie You,Huan-Ping Chao 한국화학공학회 2017 Korean Journal of Chemical Engineering Vol.34 No.6
Hydrochars derived from golden shower pod (GSH), coconut shell (CCH), and orange peel (OPH) were synthesized and applied to remove methylene green (MG5). The results indicated that the hydrochars possessed low specific surface areas (6.65-14.7m2/g), but abundant oxygen functionalities (1.69-2.12mmol/g). The hydrochars exhibited cellular and spherical morphologies. Adsorption was strongly dependent on the solution pH (2-10) and ionic strength (0-0.5M NaCl). Equilibrium can be quickly established in the kinetic study (60-120 min). The maximum Langmuir adsorption capacities at 30 oC followed the order GSH (59.6mg/g)>CCH (32.7mg/g)>OPH (15.6mg/g)> commercial glucose-prepared hydrochar (12.6mg/g). The dye adsorption efficiency was determined by the concentrations of oxygen-containing functionalities on the hydrochar surface. The adsorption process occurred spontaneously (−ΔGo) and exothermically (−ΔHo). Desorption studies confirmed the reversible adsorption process. Oxygenation of the hydrochar surface through a hydrothermal process with acrylic acid contributed to increasing MG5 adsorption and identifying the negligible role of π-π interaction to the adsorption process. The analysis of Fourier transform infrared spectrometry demonstrated that the aromatic C=C peak did not significantly decrease in intensity or shift toward higher/lower wavenumbers after adsorption, which further confirms the insignificant contribution of π-π interaction. Electrostatic attraction played a major role in adsorption mechanisms, while minor contributions were accounted for hydrogen bonding and n-π interactions. The primary adsorption mechanisms of MG5 onto hydrochar were similar to biosorbent, but dissimilar to biochar and activated carbon (i.e., π-π interaction and pore filling).
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Association Between Green Tea and Colorectal Cancer Risk: A Meta-analysis of 13 Case-control Studies
Wang, Xue-Jun,Zeng, Xian-Tao,Duan, Xiao-Li,Zeng, Huan-Chao,Shen, Rui,Zhou, Ping Asian Pacific Journal of Cancer Prevention 2012 Asian Pacific journal of cancer prevention Vol.13 No.7
Objective: Experimental studies have suggested green tea to be a chemopreventive agent for colorectal cancer, and many studies have examined possible associations. However, the conclusions were inconsistent or even contradictory, so we performed a meta-analysis based on published case-control studies to explore if green tea is indeed a protective factor. Methods: PubMed was searched up to May $10^{th}$, 2012 for relevant studies, and references of included studies were manually searched. Finally 13 eligible studies, involving 12,636 cases and 38,419 controls were identified. After data extraction, a meta-analysis was performed using CMA v2 software. Results: The results indicated there may be a weak but not statistically significant reduced risk of colorectal cancer with high dose of green tea intake (OR=0.95, 95% CI:0.81-1.11, p=0.490.69-0.98). This protective effect was also found in all subgroups, except in American and European populations. Sensitivity analysis indicated the result to be robust. Publication bias was not detected by either funnel plot or Egger tests. Conclusion: The results of this meta-analysis indicate a weak lower tendency for colorectal cancer development with green tea consumption, but available epidemiologic data are insufficient to conclude that green tea may protect against colorectal cancer in humans.
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