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        Significantly enhanced antifouling and separation capabilities of PVDF membrane by synergy of semi-interpenetrating polymer and TiO2 gel nanoparticles

        Yongdi Ma,Xi Chen,Shuai Wang,Hualin Dong,Xiaoying Zhai,Xin Shi,Jianzu Wang,Rujiang Ma,Wangqing Zhang 한국공업화학회 2022 Journal of Industrial and Engineering Chemistry Vol.108 No.-

        PVDF membrane has strong hydrophobicity and low anti-pollution performance, greatly limiting its practicalapplication. These drawbacks have been successfully overcome by designing and then preparing amembrane with a semi-interpenetrating polymer (semi-IPN) of PVDF/poly(acrylic acid) (PAA) as themembrane matrix, TiO2 nanoparticles as functional components and F127 as pore-forming agent. Thesemi-IPN was prepared by copolymerizing acrylic acid with N,N methyl acrylamide in the presence ofPVDF, and the TiO2 gel nanoparticles were in situ formed in the membrane-forming process. The propertiesof the composite membrane were significantly affected by the semi-IPN, F127 and TiO2. By adjustingthe membrane structure with the semi-IPN, F127 and TiO2 nanoparticles, we prepared a composite membranewith a water contact angle of 40, a BSA rejection ratio of 87.5% and a water flux of 802.5 L/m2/h/bar. After a simple UV irradiation, the water flux of this composite membrane rose to 1030 L/m2/h/bar,without any rejection decline. The membrane contaminated by humic acid could recover the water fluxup to above 95.3% of its original value by a single UV irradiation, showing a very good antifouling performance. In addition, the composite membrane also exhibited a very strong pollution resistance and separationperformance for bovine serum albumin and oil-water emulsion. All in all, based on the synergy ofthe semi-IPN and the evenly dispersed TiO2 nanoparticles, the prepared composite membrane exhibitedexcellent comprehensive properties and demonstrated a great potential for various separationapplications.

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        Stochastic elastic wave analysis of angled beams

        Changqing Bai,Hualin Ma,Victor P.W. Shim 국제구조공학회 2015 Structural Engineering and Mechanics, An Int'l Jou Vol.56 No.5

        The stochastic finite element method is employed to obtain a stochastic dynamic model of angled beams subjected to impact loads when uncertain material properties are described by random fields. Using the perturbation technique in conjunction with a precise time integration method, a random analysis approach is developed for efficient analysis of random elastic waves. Formulas for the mean, variance and covariance of displacement, strain and stress are introduced. Statistics of displacement and stress waves is analyzed and effects of bend angle and material stochasticity on wave propagation are studied. It is found that the elastic wave correlation in the angled section is the most significant. The mean, variance and covariance of the stress wave amplitude decrease with an increase in bend angle. The standard deviation of the beam material density plays an important role in longitudinal displacement wave covariance.

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