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        Structure and Microwave Absorption Properties of Polyaniline/Zn Ferrite Composites

        Honglong Xing,Ye Liu,Zhenfeng Liu,Huan Wang,Hanxiao Jia 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2018 NANO Vol.13 No.09

        Polyaniline (PANI)/Zn ferrite composites were fabricated by simple two-step method. The crystal phase, particle size, morphology, thermal stability and conductivity were characterized. Electromagnetic parameters of PANI/Zn ferrite composites were measured at room temperature in the frequency of 2–18 GHz. The prepared composite had an amorphous fluffy structure, Zn ferrite nanoparticles with diameters ranging from 20 nm to 30 nm are encapsulated in PANI or on PANI surface, and the thermal stability of the composite is poor. But Zn ferrite content plays a key role in influencing this structure and regulating microwave attenuation capability. The PANI/Zn ferrite composites showed an enhanced microwave absorption performance in Ku band at thin coating thickness which corresponds to RL value below - 10 dB and the minimum reflection loss (RL) is - 54.4 dB at 17.6 GHz with the coating thickness of 1.4 mm.

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        Novel Microwave Absorption Materials of Porous Flower-Like Nickel Oxide@Polyaniline in the X-Band

        Ye Liu,Honglong Xing,Lei Wang,Zhenfeng Liu,Huan Wang,Hanxiao Jia 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2018 NANO Vol.13 No.6

        Porous flower nickel oxide@polyaniline (NiO@PANI) composites as excellent microwave absorption (MA) materials in the X-band were synthesized via a two-step strategy in this work. The porous NiO flower is uniformly dispersed and homogeneous in particle size after Ostwald ripening process. Coating conductive PANI on the surface of porous NiO microspheres could improve interfacial polarization and dielectric loss property that will lead to a great improvement of MA properties. Electromagnetic (EM) parameters of NiO@PANI composites with different NiO contents were investigated by a vector network analyzer and the reflection loss (RL) values with varied thickness were also calculated. The results showed that the effective absorption bandwidths (RL < -10 dB) of all NiO@PANI composites can cover the whole X-band. Especially, the NiO@PANI0.1 composite is able to attenuate microwave energy in the X-band with the thickness of 2.5mm. The NiO@PANI0.2 has a maximum RL of -32.8 dB at 10.1GHz and the effective absorption bandwidths cover 4.64GHz (11.12–15.76GHz) at 2.0mm. The excellent MA absorption performance may be ascribed to the polarization effect, dielectric loss and structure of porous flower-like NiO@PANI. Our work confirms that the synthesized NiO@PANI composite is an attractive candidate as a highly efficient MA material in the X-band.

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