http://chineseinput.net/에서 pinyin(병음)방식으로 중국어를 변환할 수 있습니다.
변환된 중국어를 복사하여 사용하시면 됩니다.
Xiaoyu Li,Juan Chen,Shouyan Chen,Chunmei Lu,Guangqian Luo,Hong Yao 한국공업화학회 2021 Journal of Industrial and Engineering Chemistry Vol.101 No.-
Impact of arsenic on the performance of Mg-Ti modified iron-based catalyst during selective catalyticreduction of NOx with ammonia was studied. The results indicated that Mg and Ti modification not onlyimproved the catalytic activity at 100–350 C, but also exhibited remarkable anti-arsenic ability. Mg wasdominant in the excellent anti-arsenic performance, and this role was firstly recognized. The anti-arsenicmechanism of Mg-Ti modified iron-based catalyst was ascribed to two aspects. One side, Mg exhibitedwell reactivity with arsenic which competed with Fe for the adsorption of arsenic and protected activeiron sites from arsenic occupation. The other side, presence of Mg promoted the formation of MgFe2O4in view of the strong interactions between Mg and Fe, suppressing the interactions between arsenicand Fe. Instead, gaseous arsenic turned to bond with Mg-O sites. Consequently, surface acid sites andfunction Fe-OH/ Fe = O bonds were preserved for de-NOx. Moreover, increase of oxygen content and temperatureweakened the deactivation of Mg-Ti modified iron-based catalyst by arsenic. It was due to theoxidation of As2O3 with oxygen content increase and the strengthened reactivity of non-active iron siteswith arsenic and Mg with arsenic as temperature elevation, inhibiting the interactions between activeiron sites with arsenic.