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Effect of melt temperature on the mechanical properties of bulk metallic glasses
Kumar, Golden,Ohkubo, Tadakatsu,Hono, Kazuhiro Cambridge University Press (Materials Research Soc 2009 Journal of materials research Vol.24 No.7
<P>The effect of melt temperature on the structure and mechanical properties of three Zr-based bulk metallic glasses (BMGs)-Zr62Cu17Ni13Al8, Zr55Cu20Ni10Al10Ti5, and Zr52.5Cu17.9Ni14.6Al10Ti5 (Vit105)-has been studied. The results show that the BMGs cast from higher melt temperature exhibit large plastic strains despite their amorphous structure. The samples become macroscopically brittle when the quenched-in crystals form an interconnected microstructure. In contrast to previous studies, there is no notable effect on the Poisson’s ratio (ν) and other elastic constants.</P>
Nanocomposite Magnetic Materials
Ludwig Schultz,Alberto Bollero,Axel Handstein,Dietrich Hinz,Karl-Hartmut Muller,Golden Kumar,Juergen Eckert,Oliver Gutfleisch,Anke Kirehner Aru Yan The Korean Powder Metallurgy Institute 2002 한국분말재료학회지 (KPMI) Vol.9 No.6
Recent developments in nanocrystalline and nanocomposite rare earth-transition metal magnets are reviewed and emphasis is placed on research work at IFW Dresden. Principal synthesis methods include high energy ball milling, melt spinning, mold casting and hydrogen assisted methods such as reactive milling and hydrogenation-disproportionation-desorption-recombination. These techniques are applied to NdFeB-, PrFeB- and SmCo-type systems with the aim to produce high remanence magnets with high coercivity. Concepts of maximizing the energy density in nanostructured magnets by either inducing a texture via anisotropic HDDR or hot deformation or enhancing the remanence via magnetic exchange coupling are evaluated. With respect to high temperature applications melt spun $Sm(Co_{0.74}Fe_{0.1}Cu_{0.12}Zr_{0.04})_{7.5}$ ribbons were prepared, which showed coercivities of up to 0.53 T at 50$0^{\circ}C$. Partially amorphous $Nd_{60}Fe_xCo_{30-x}Al_{10}(0{\leq}x{\leq}30)$ alloys were prepared by copper mold casting. The effect of transition metal content on the glass-forming ability and the magnetic properties was investigated. The $Nd_{60}Co_{30}Al_{10}$ alloy exhibits an amorphous structure shown by the corresponding diffraction pattern. A small substitution of Co by 2.5 at.% Fe results In the formation of Fe-rich crystallites embedded in the Nd-rich amorphous matrix. The Fe-rich crystallites show hard magnetic behaviour at room temperature with a coercivity value of about 0.4 T, relatively low saturation magnetization and a Curie temperature of 500 K.