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Efficient bipolar membrane with protein interfacial layer for optimal water splitting
Murli Manohar,Geetanjali Shukla,Ravi P. Pandey,Vinod K. Shahi 한국공업화학회 2017 Journal of Industrial and Engineering Chemistry Vol.47 No.-
Herein, we are reporting bipolar membranes (BPMs) for water splitting. BPMs are sandwiched structureof anion-exchange layer (AEL) and cation-exchange layer (CEL) with a protein (lysozyme (LYS) or bovineserum albumin (BSA) as interfacial layer (IL). CEL and AEL were prepared by controlled sulphonation orchloromethylation (without chloromethyl methyl ether). Presence of acidic and basic groups in the ILfacilitates the H+/OH transport and act as proton/hydroxide buffer. Further, water dissociation efficiencyof BPMs was also analysed by experimental results (I–V curves, chronopotentiometry, and electrodialy-sis). Data revealed high suitability of BPM-LYS for excellent catalytic activity and water dissociation. Theexperimental results (I–V) curves, chronopotentiometry, and electrodialysis) revealed high suitability ofBPM-LYS for excellent catalytic activity and water dissociation.