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RISS 인기검색어
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- 저자 : Farid Hafiz Muhammad (검색결과 3 건)
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Abdullah Muhammad,Alharbi Fatemah Farraj,Khosa Rabia Yasmin,Alburaih Huda A.,Manzoor Sumaira,Abid Abdul Ghafoor,Ali Haitham Elhosiny,Waheed Muhammad Suleman,Ansari Muhammad Numair,Farid Hafiz Muhammad 한국화학공학회 2023 Korean Journal of Chemical Engineering Vol.40 No.6
Manganese ferrite offers several advantages when employed as an electrocatalytic material for supercapacitors, including outstanding cycle stability and energy capacity. When compared to identical-metal sulfides, specific capacitance (Csp) of MnFe2O4 remains inadequate. So, using the hydrothermal synthesis technique, partial sulfur doping of MnFe2O4 was achieved to investigate the synergetic effect of oxides and sulfides. Various spectroscopic and microscopic studies demonstrate that adding sulfur atoms into MnFe2O4 increases the lattice parameters, which improves electrochemical performance. At a current density around 2 A g−1, then calculating MnFe2O4 with partial sulfur doping has a Csp of 1,201.60 F g−1, that is greater than 784.0 F g−1 of pure MnFe2O4. Maximum energy density (Ed) of 93.62 Wh kg−1 was produced with a power density (Pd) of 749 W kg−1. The current study depicts that partial sulfur doping can enhance the electrochemical behavior of MnFe2O4. As a result, the present work shows more effective in field of energy storage by enhancing their poor electrochemical performance.
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Designing CuSe-gCN nanocomposite as an active electrocatalyst for water oxidation
Alharbi Fatemah Farraj,Ahmad Zahoor,Chughtai Adeel Hussain,Khosa Rabia Yasmin,Farid Hafiz Muhammad Tahir 한국화학공학회 2023 Korean Journal of Chemical Engineering Vol.40 No.9
CuSe-gCN nanocrystals were premeditated and produced utilizing a simple hydrothermal method. Different analytical techniques well characterized the generated samples. The prepared samples also contain nanocrystals with a vertical shape, decorated with numerous nanoparticles. All characterizations confirm the phase composition of composite CuSe-gCN. The pore size of the N2 adsorption-desorption isotherm also pointed to a mesoporous structure. Furthermore, the combination of distinct morphology nanoparticles embellished on gCN graphitized nanotubes helps to achieve larger current densities and lower starting potentials for the oxygen evolution process. Because of their unique mesoporous structure, the CuSe-gCN catalysts show exceptional electrical conductivity and electrocatalytic activity. Compared to monometallic CuSe and gCN, CuSe-gCN significantly lower overpotential of 208 mV was needed to obtain a current density of 10 mA/cm2. The CuSe-gCN nanocrystals displayed good stability and a low Tafel slope of 35 mV/dec. This research shows that it is possible to use a copper-based selenide with gCN and combine all the beneficial characteristics in a single catalyst system.. Still, it also offers fresh perspectives on the logical proposal and creation of effective electrocatalysts for various applications.
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Alenad Asma M.,Fatima Sofia,Khalid Usman,Bano Nigarish,Abid Abdul Ghafoor,Manzoor Sumaira,Farid Hafiz Muhammad Tahir,Messali Mouslim,Alzahrani Huda A.,Taha Taha Abdel Mohaymen 한국세라믹학회 2023 한국세라믹학회지 Vol.60 No.5
Hydrogen is the ideal future fuel, since it is clean, saves energy, and is abundant in nature. Though there are several methods for producing hydrogen, only a few of them are environmentally friendly. To employ water electrolysis to make hydrogen and solve the energy shortage problem, highly active electrocatalysts must be created. Zinc sulphide/polyaniline (ZnS/PANI) nanocomposite was successfully produced using a straightforward two-step coprecipitation and polymerization procedure. Different analyses were used to characterize the fabricated materials. The findings show that the ZnS/PANI nanocomposite's morphology has a consistent porous shape, and the electrical structure of the active sites determines how well catalysts can make contact with the intermediates. Multiple attempts have been made to create the most affordable, functional electrocatalyst for oxygen evolution reactions (OER). However, clean energy production from such materials is sluggish. In comparison to pure PANI nanofibers (143.14 m2 g−1 and 0.4827 nm) and ZnS nanostructures (249.85 m2 g−1 and 0.4224 nm), the composite ZnS/PANI displays a greater Brunauer–Emmett–Teller (BET) surface area around 372.65 m2 g−1 along with nanoporous size of 0.393 nm due to the interaction, which provides distinctive features in contrast to ZnS and PANI. Synergistically, composite ZnS/PANI indicates lower overpotentials of 132 mV for oxygen evolution performance at 10 mA cm−2. An improved OER activity is observed by composite ZnS/PANIs as high current density, lower overpotential and reduced Tafel value of 53 mV dec−1. This catalyst also exhibited a significant double-layer capacitance and a large electrochemically active surface area. ZnS/PANI is a magnificent electrocatalyst for oxygen evolution.
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