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Crystal Structure of Monoclinic RbD2PO4 in the Ferrielectric Phase
Eisuke Magome,M Komuke,M Machida 한국물리학회 2007 THE JOURNAL OF THE KOREAN PHYSICAL SOCIETY Vol.51 No.2I
We determined the crystal structure of monoclinic RbD2PO4 in the ferrielectric phase (phase III) by means of neutron diffraction measurements. The structure refinement converged at Rw = 0.0594. The deuterium atoms associated with the hydrogen bonds along the b axis are ordered in phase III. There are four kinds of PO4 tetrahedra in phase III. We show that the ferrielectricity of phase III is explained by four kinds of PO4 tetrahedra.?