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Coupled Lattice Polarization and Ferromagnetism in Multiferroic NiTiO<sub>3</sub> Thin Films
Varga, Tamas,Droubay, Timothy C.,Kovarik, Libor,Nandasiri, Manjula I.,Shutthanandan, Vaithiyalingam,Hu, Dehong,Kim, Bumsoo,Jeon, Seokwoo,Hong, Seungbum,Li, Yulan,Chambers, Scott A. American Chemical Society 2017 ACS APPLIED MATERIALS & INTERFACES Vol.9 No.26
<P>Polarization-induced weak ferromagnetism (WFM) was demonstrated a few years back in LiNbO3-type compounds, MTiO3 (M = Fe, Mn, Ni). Although the coexistence of ferroelectric polarization and ferromagnetism has been demonstrated in this rare multiferroic family before, first in bulk FeTiO3, then in thin-film NiTiO3, the coupling of the two order parameters has not been confirmed Here, we report the stabilization of polar, ferromagnetic NiTiO3 by oxide epitaxy on a LiNbO3 substrate utilizing tensile strain and demonstrate the theoretically predicted coupling between its polarization and ferromagnetism by X-ray magnetic circular dichroism under applied fields. The experimentally observed direction of ferroic ordering in the film is supported by simulations using the phase-field approach. Our work validates symmetry-based criteria and first-principles calculations of the coexistence of ferroelectricity and WFM in MTiO3 transition metal titanates crystallizing in the LiNbO3 structure. It also demonstrates the applicability of epitaxial strain as a viable alternative to high-pressure crystal growth to stabilize metastable materials and a valuable tuning parameter to simultaneously control two ferroic order parameters to create a multiferroic. Multiferroic NiTiO3 has potential applications in spintronics where ferroic switching is used, such as new four-stage memories and electromagnetic switches.</P>