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Reaction Route to the Crystallization of Copper Oxides
Kunfeng Chen,Dongfeng Xue 한국진공학회 2014 Applied Science and Convergence Technology Vol.23 No.1
Copper is an important component from coin metal to electronic wire, integrated circuit, and to lithium battery. Copper oxides, mainly including Cu2O and CuO, are important semiconductors for the wide applications in solar cell, catalysis, lithium-ion battery, and sensor. Due to their low cost, low toxicity, and easy synthesis, copper oxides have received much research interest in recent year. Herein, we review the crystallization of copper oxides by designing various chemical reaction routes, for example, the synthesis of Cu2O by reduction route, the oxidation of copper to Cu2O or CuO, the chemical transformation of Cu2O to CuO, the chemical precipitation of CuO. In the designed reaction system, ligands, pH, inorganic ions, temperature were used to control both chemical reactions and the crystallization processes, which finally determined the phases, morphologies and sizes of copper oxides. Furthermore, copper oxides with different structures as electrode materials for lithium-ion batteries were also reviewed. This review presents a simple route to study the reactioncrystallization- performance relationship of Cu-based materials, which can be extended to other inorganic oxides.
Reaction Route to the Crystallization of Copper Oxides
Chen, Kunfeng,Xue, Dongfeng The Korean Vacuum Society 2014 Applied Science and Convergence Technology Vol.23 No.1
Copper is an important component from coin metal to electronic wire, integrated circuit, and to lithium battery. Copper oxides, mainly including $Cu_2O$ and CuO, are important semiconductors for the wide applications in solar cell, catalysis, lithium-ion battery, and sensor. Due to their low cost, low toxicity, and easy synthesis, copper oxides have received much research interest in recent year. Herein, we review the crystallization of copper oxides by designing various chemical reaction routes, for example, the synthesis of $Cu_2O$ by reduction route, the oxidation of copper to $Cu_2O$ or CuO, the chemical transformation of $Cu_2O$ to CuO, the chemical precipitation of CuO. In the designed reaction system, ligands, pH, inorganic ions, temperature were used to control both chemical reactions and the crystallization processes, which finally determined the phases, morphologies and sizes of copper oxides. Furthermore, copper oxides with different structures as electrode materials for lithium-ion batteries were also reviewed. This review presents a simple route to study the reaction-crystallization-performance relationship of Cu-based materials, which can be extended to other inorganic oxides.
Preparation of bovine hydroxyapatite by transferred arc plasma
C.P. Yoganand,V. Selvarajan,O.M. Goudouri,K.M. Paraskevopoulos,Junshu Wu,Dongfeng Xue 한국물리학회 2011 Current Applied Physics Vol.11 No.3
Hydroxyapatite (Ca_10(PO_4)_6(OH)_2, abbreviated as HA) is a kind of bioactive material that has received considerable attention over the past decades as an implant material due to its excellent biocompatability for clinical applications. In this work, Hydroxyapatite was obtained by plasma processing of the natural bovine bones by Transferred arc plasma (TAP) processing at 5 kW in argon plasma for different processing times (i.e. 30, 45, 60, 90 and 120 s). The TAP synthesized HA bioceramic was characterized by XRD, FTIR,SEM-EDX and TG-DTA analysis. The effect of TAP processing time on the preparation of organic free HA from bovine bone was studied. The study indicated that TAP processing for 30, 45 and 60 s were insuf-ficient for removal of organics from the natural bovine bone. Organic free bovine HA was obtained for 90 s TAP processing with a Ca/P ratio of 1.93 comparable with commercially available natural HA-Endobon powder. Whereas 120 s of processing resulted in trivial thermal decomposition of HA in to its constituent phases. Thus our present investigation suggested that HA production from bovine bone using TAP processing is a time effective advantageous method in comparison to the annealing method.