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Tanaka Kotaro, Korea, and the Natural Law
( Kevin M. Doak ) 성균관대학교 동아시아학술원 2017 Sungkyun Journal of East Asian Studies Vol.17 No.1
Tanaka Ko taro 田中耕太郎 (1890-1974) was one of the most important jurists of modern Japan. A widely travelled globalist intellectual, he is generally seen as culturally oriented toward the West. Yet his own contribution to international jurisprudence, his theory of World Law, is essentially globalist and critical of the Western imperialism implicit in the dominant strain of modern international law. In spite of the globalist implications of Tanaka`s jurisprudence, there has been no attention to his relationship with Korea. This paper pioneers a study of Tanaka and Korea, focusing on two visits he made there in 1932 and in 1943. Outlining Tanaka`s key ideas on world law and the Natural Law, the subjects of lectures he gave at Keijo Imperial University, it raises the question about whether Tanaka might have influenced faculty and students of law at Keijo Imperial University and possibly laid the groundwork for Korea`s greatest Natural Law theorist Hwang Sandok 黃山德 (1917-1989). It also introduces, through Tanaka`s ideas on World Law, an alternative to the “colonialist/nationalist” paradigm that influences much of historical writing about the Korean-Japanese historical relationship.
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Jeon, Seokmin,Kim, Minho,Doak, Peter W.,Atwater, Harry A.,Kim, Hyungjun American Chemical Society 2019 JOURNAL OF PHYSICAL CHEMISTRY C - Vol.123 No.5
<P>The adsorption and decomposition mechanisms for 1-propanethiol on a Ga-rich GaP(001) (2 × 4) surface are investigated at an atomic level using scanning tunneling microscopy (STM), X-ray photoelectron spectroscopy, and density functional theory (DFT) calculations. Using a combination of experimental and theoretical tools, we probe the detailed structures and energetics of a series of reaction intermediates in the thermal decomposition pathway from 130 to 773 K. At 130 K, the propanethiolate adsorbates are observed at the edge gallium sites, with the thiolate-Ga bonding configuration maintained up to 473 K. Further decomposition produces two new surface features, Ga-S-Ga and P-propyl species at 573 K. Finally, S-induced (1 × 1) and (2 × 1) reconstructions are observed at 673-773 K, which are reportedly associated with arrays of surface Ga-S-Ga bonds and subsurface diffusion of S. To understand the observed site-selectivity on the hydrogen dissociation of the thiol molecule at 130 K, the two most likely dissociation pathways (Ga-P vs Ga-Ga dimer sites) are investigated using DFT Gibbs energy calculations. While the theory predicts the kinetic advantage for the dissociation reaction occurring on the Ga-P dimer (Lewis acid-base combination), we only observed dissociation products on the Ga-Ga dimer (Lewis acid). The DFT calculations clarify that the reversible thiolate diffusion along the Ga dimer row prevents recombinative desorption, which is probable on the Ga-P dimer. Together with experimental and theoretical results, we suggest a thermal decomposition mechanism for the thiol molecule with atomic-level structural details.</P> [FIG OMISSION]</BR>
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