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        Inverted structure perovskite solar cells: A theoretical study

        Anurag Sahu,Ambesh Dixit 한국물리학회 2018 Current Applied Physics Vol.18 No.12

        We analysed perovskite CH3NH3PbI3-xClx inverted planer structure solar cell with nickel oxide (NiO) and spiro- MeOTAD as hole conductors. This structure is free from electron transport layer. The thickness is optimized for NiO and spiro-MeOTAD hole conducting materials and the devices do not exhibit any significant variation for both hole transport materials. The back metal contact work function is varied for NiO hole conductor and observed that Ni and Co metals may be suitable back contacts for efficient carrier dynamics. The solar photovoltaic response showed a linear decrease in efficiency with increasing temperature. The electron affinity and band gap of transparent conducting oxide and NiO layers are varied to understand their impact on conduction and valence band offsets. A range of suitable band gap and electron affinity values are found essential for efficient device performance.

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        Catalyst free rutile phase TiO2 nanorods as efficient hydrogen sensor with enhanced sensitivity and selectivity

        Prakash Chandra,Dixit Ambesh 한국물리학회 2022 Current Applied Physics Vol.41 No.-

        Using a low-cost hydrothermal method, we demonstrated the fabrication of phase pure rutile phase high-density vertically aligned TiO2 nanorods-based catalyst-free hydrogen (H2) gas sensor. The synthesized TiO2 nanorods on FTO are decorated with the aluminum interdigitated electrode pattern for electrical measurements. TiO2 nanorods-based hydrogen sensor showed the optimum response of ~53.18% at 150 ppm H2 concentration relative to air at 100 ◦C. The measured response and recovery time of TiO2 nanorods are 85 and 620 s, respectively. The TiO2 nanorods-based H2 gas sensor showed a relatively better response, good reproducibility, and stability at moderate temperatures, i.e., 50 and 100 ◦C. The electrochemical impedance measurements showed a small variation in the surface characteristics of TiO2 nanorods before and after exposing H2 gas. The carrier lifetime at 50 ◦C and 100 ◦C at 150 ppm are 5 μs and 3 μs, respectively. Interestingly, H2 selectivity is also observed against H2S, CO, and NH3 gases, suggesting that high-density vertically aligned TiO2 nanorods can be a good candidate for efficient hydrogen sensing at relatively low temperatures.

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