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        Blue organic light-emitting diodes with 2-methyl-9,10- bis(naphthalen-2-yl)anthracene as hole transport and emitting layer and the impedance spectroscopy analysis

        Xiao-Wen Zhang,Bing-Jie Mo,Li-Ming Liu,Hong-Hang Wang,Dan-Teng Chang,Ji-Wen Xu,Hua Wang,Bin Wei 한국물리학회 2014 Current Applied Physics Vol.14 No.11

        2-methyl-9,10-bis(naphthalen-2-yl)anthracene (MADN) based fluorescent blue organic light-emitting diodes (OLEDs) are demonstrated. With MADN as emitting layer, experiments indicate that thick MADN (40e60 nm) is preferable for constructing efficient blue OLED. With MADN as hole-transport and emitting layer and tris(8-hydroxy-quinolinato)aluminium (Alq3) as electron-transport layer, the OLED electroluminescent characteristics show a mixture emission of MADN and Alq3 with Commission Internationale d'Eclairage (CIE) color coordinates of (0.25, 0.34), indicating feasible hole transporting in MADN. Using 4,7-diphenyl-1,10-phenanthroline (BPhen) replacing Alq3 as electron-transport layer, the OLED shows deep blue emission with a maximum luminous efficiency of 4.8 cd/A and CIE color coordinates of (0.16, 0.09). The hole transport characteristics of MADN are further clarified by constructing hole-only device and performing impedance spectroscopy analysis. The results indicate that MADN shows superior hole-transport ability which is almost comparable to typical hole-transport material of N,N0-bis(naphthalen-1-yl)-N,N0-bis(phenyl)-benzidine (NPB), suggesting a promising application for constructing efficient blue OLED with integrated hole-transport layer and emitting layer.

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