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- 저자 : Chuanqiang Li (검색결과 2 건)
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Effect of Li Content on the Surface Film Formed on the Binary Mg–Li Alloys in NaCl Solution
Chuanqiang Li,Dahui Liang,Yejia Lin,Yong Dong,Binqing Shi,Changjian Yan,Zhengrong Zhang 대한금속·재료학회 2024 METALS AND MATERIALS International Vol.30 No.1
The surface film formed on the Mg–Li alloys with different Li content in 0.1 M NaCl solution were investigated via electrochemicaltesting, morphologies observation and chemical composition analysis in this work. The results revealed that thesurface film of Mg–14Li alloy (L14: body centred cubic (BCC)) possessed higher electrical resistivity and remained a highertolerating over-potential (0.1 V vs. open circuit potential) than those of Mg–4Li (L4: hexagonal closed-packed (HCP)) andMg–7.5Li (L7: HCP+BCC), resulting in a better corrosion performance. After 24 h immersion in NaCl solution, the wholesurface film of L14 remained undamaged and displayed weave-like and dense characteristic, while both L4 and L7 present aseverely damaged film. The cross-sectional details illustrated typical two layers of surface film formed on L14 with the outerlayer of ~ 1.5 μm and inner layer of ~ 2.5 μm in thickness, whilst only one layer of film with less than 2.5 μm in thicknesswas observed on L4 and L7. At last, combining analysis of X-ray diffraction, energy dispersive X-ray spectrometry, X-rayphotoelectron spectroscopy and transmission electron microscope confirmed the composition of outer layer of surface filmon the L14 contains much more Mg(OH)2 and Li-containing compounds, and the porous Mg(OH)2 film can be sealed by theLi-containing compounds, which is very different the single Mg(OH)2 film on the traditional magnesium and L4/L7 alloys. As a result, the best protective function of the surface film on the L14 alloy contribute to its high corrosion resistance.
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Shougang Duan,Yufeng Yang,Yong Dong,Yu Wang,Beibei Jiang,Chuanqiang Li,Zhengrong Zhang 대한금속·재료학회 2023 METALS AND MATERIALS International Vol.29 No.6
Ultra-fine grain AlCrFe2Ni2Wx(x = 0.1, 0.2, 0.3, 0.4) alloys were designed and prepared by vacuum arc melting, and correspondingmicrostructural evolution and mechanical properties were investigated. All of the alloys show a mixed structurewith FCC + BCC (B2) + TCP phases. The addition of W element has a significant effect on the formation mechanism of themorphology, which promotes the transition from FCC phase to μ phase and inhibits the spinodal decomposition of BCCphase. With the increase of W content, more μ phase precipitates from the FCC phase and grain boundaries. After the dissolutionof W element into matrix, the formed oversaturated solid solution and precipitated μ phase have the effect of solidsolution strengthening and second phase strengthening, respectively. The yield strength and Vickers hardness increasesfrom 765 to 1319.6 MPa and HV 332.2 to HV 461.8, respectively. The addition of W element enhances the strength of thealloys but reduced ductility. The AlCrFe2Ni2W0.1alloy exhibits outstanding comprehensive mechanical properties, with itsfracture strength reaching 2726.5 MPa and a considerable compressive strain of 43.3%, which implies promising potentialengineering application.
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