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        Fabrication of ZnO electroceramics by reaction bonding

        Enrique Rocha-Rangel,Octavio Martínez-Urgell,Carlos Gómez-Yánez 한양대학교 세라믹연구소 2006 Journal of Ceramic Processing Research Vol.7 No.3

        ZnO ceramics doped with small amounts of Bi2O3, CoO, MnO, Sb2O3 and Cr2O3 offer a great potential as electroceramic materials to be used as protectors to prevent electric surges. In the present communication, the reaction bonded alumina oxide (RBAO) technique is adapted for the production of ZnO-based ceramics by the reaction bonding zinc oxide (RBZnO) process with the idea of achieving the advantages of the RBAO process. Because Zn oxidation occurs between 330 °C and 468 °C, slow heating rates before the Zn melting point (419 °C) is very important in order to obtain the desired ceramic. The need for a fine microstructure of the matrix with many grain boundaries is discussed. ZnO ceramics doped with small amounts of Bi2O3, CoO, MnO, Sb2O3 and Cr2O3 offer a great potential as electroceramic materials to be used as protectors to prevent electric surges. In the present communication, the reaction bonded alumina oxide (RBAO) technique is adapted for the production of ZnO-based ceramics by the reaction bonding zinc oxide (RBZnO) process with the idea of achieving the advantages of the RBAO process. Because Zn oxidation occurs between 330 °C and 468 °C, slow heating rates before the Zn melting point (419 °C) is very important in order to obtain the desired ceramic. The need for a fine microstructure of the matrix with many grain boundaries is discussed.

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        Enhanced CO2 capture by cupuassu shell-derived activated carbon with high microporous volume

        Cruz Orlando F.,Campello-Gómez Ignacio,Casco Mirian E.,Serafin Jarosław,Silvestre-Albero Joaquín,Martínez-Escandell Manuel,Hotza Dachamir,Rambo Carlos R. 한국탄소학회 2023 Carbon Letters Vol.33 No.3

        Here, we report the preparation of microporous-activated carbons from a Brazilian natural lignocellulosic agricultural waste, cupuassu shell, by pyrolysis at 500 ºC and KOH activation under different experimental conditions and their subsequent application as adsorbent for CO2 capture. The effect of the KOH:precursor ratio (wt/wt%) and the activation temperature on the porous texture of activated carbons have been studied. The values of specific surface area ranged from 1132 to 2486 m2/g, and the overall micropore volume ranged from 0.73 to 1.02 cm3/g. Carbons activated with 2:1 ratio of KOH and activation temperature of 700 ºC presented a CO2 adsorption at 1 bar of 7.8 and 4.4 mmol/g at 0 °C and 25 ºC, respectively. The isosteric heat of adsorption, Qst , was calculated for all samples by applying the Clausius–Clapeyron approach to CO2 adsorption isotherms at both temperatures. The values of CO2 adsorption capacities are among the highest reported in the literature, especially for activated carbons produced from biomass.

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        Effect of tumor burden and radical surgery on survival difference between upfront, early interval or delayed cytoreductive surgery in ovarian cancer

        Martina Aida Angeles,Bastien Cabarrou,Antonio Gil-Moreno,Asunción Pérez-Benavente,Emanuela Spagnolo,Agnieszka Rychlik,Carlos Martínez-Gómez,Frédéric Guyon,Ignacio Zapardiel,Denis Querleu,Claire Illac 대한부인종양학회 2021 Journal of Gynecologic Oncology Vol.32 No.6

        Objective: We sought to evaluate the impact on survival of tumor burden and surgical complexity in relation to the number of cycles of neoadjuvant chemotherapy (NACT) in patients with advanced ovarian cancer (OC) with minimal (CC-1) or no residual disease (CC-0). Methods: This retrospective study included patients with International Federation of Gynaecology and Obstetrics IIIC–IV stage OC who underwent debulking surgery at 4 high- volume institutions between January 2008 and December 2015. We assessed the overall survival (OS) of primary debulking surgery (PDS group), early interval debulking surgery after 3–4 cycles of NACT (early IDS group) and delayed debulking surgery after 6 cycles (DDS group) with CC-0 or CC-1 according to peritoneal cancer index (PCI) and Aletti score. Results: Five hundred forty-nine women were included: 175 (31.9%) had PDS, 224 (40.8%) early IDS and 150 (27.3%) DDS. Regardless of Aletti score, median OS after PDS was significantly higher than after early IDS or DDS, but the survival difference was higher in women with an Aletti score <8. Among patients with PCI ≤10, median OS after PDS was significantly higher than after early IDS or DDS. In women with PCI >10, there were no differences between PDS and early IDS, but DDS was associated with decreased OS. Conclusion: The benefit of complete PDS compared with NACT was maximal in patients with a low complexity score. In patients with low tumor burden, there was a survival benefit of PDS over early IDS or DDS. In women with high tumor load, DDS impaired the oncological outcome.

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