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Huixiang Wu,CHANGJUN HOU,Huanbao Fa,Liang Dong,Yi Ma,Mei Yang,Caihong Shen,Jun Zhou,DANQUN HUO 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2016 NANO Vol.11 No.7
Cartap is among the most popular pesticides that are widely used to boost food production, however, its residues pose a great threat to human health and the environment. We presented simple and effective colorimetric sensor based on aggregation of gold nanoparticles (AuNPs) with appropriate diameter and fluorescent sensor via inner filter effect (IFE) of AuNPs on cadmium telluride quantum dots (CdTe QDs), respectively. Firstly, effect of diameter of AuNPs was investigated and the results indicated that AuNPs with diameter of 13 nm (AuNPs13nm) showed better sensitivity toward cartap. Thus, AuNPs13nm was chosen for colorimetric and fluorescent cartap assay. On one hand, mercaptoacetic acid (MA) was functionalized on AuNPs13nm for the improvement of anti-disturbance ability for discrimination study. A decent linear relationship for cartap was obtained in the range from 1 µM to 50 µM with detection limit of 1.32 µM for colorimetric readout; on the other hand, fluorescent sensor based on AuNPs13nm displayed excellent linear relationship with cartap concentration varying from 20 nM to 100 nM with low detection limit of 4.02 nM. And the above-mentioned sensor showed acceptable anti-disturbance ability for cartap discrimination. These results demonstrated that the sensor as-developed would be a great potential candidate for cartap detection in real application.
Persistent Charge-Density-Wave Order in Single-Layer TaSe<sub>2</sub>
Ryu, Hyejin,Chen, Yi,Kim, Heejung,Tsai, Hsin-Zon,Tang, Shujie,Jiang, Juan,Liou, Franklin,Kahn, Salman,Jia, Caihong,Omrani, Arash A.,Shim, Ji Hoon,Hussain, Zahid,Shen, Zhi-Xun,Kim, Kyoo,Min, Byung Il,H American Chemical Society 2018 NANO LETTERS Vol.18 No.2
<P>We present the electronic characterization of single-layer 1H-TaSe2 grown by molecular beam epitaxy using a combined angle-resolved photoeinission spectroscopy, scanning tunneling microscopy/spectroscopy, and density functional theory calculations. We demonstrate that 3 x 3 charge-density-wave (CDW) order persists despite distinct changes in the low energy electronic. structure highlighted by the reduction in the number of-bands crossing the Fermi energy and the corresponding modification Of Fermi surface topology. Enhanced, spin-orbit coupling and lattice distortion in the single-layer play a crucial role in the formation of CDW order. Our findings provide a deeper understanding of the nature of COW order in the two-dimensional limit.</P>
Charge density wave order in 2D transition metal dichalcogenides
Hyejin Ryu,Yi Chen,Miguel M. Ugeda,Heejung Kim,Yi Zhang,Hsin-Zon Tsai,Shujie Tang,Juan Jiang,Franklin Liou,Salman Kahn,Caihong Jia,Arash A. Omrani,Ji Hoon Shim,Zahid Hussain,Zhi-Xun Shen,Kyoo Kim,Byun 한국진공학회 2018 한국진공학회 학술발표회초록집 Vol.2018 No.2