Purge & Trap, GC/MSD를 이용한 해수 중 휘발성유기화학물질 분석

김유곤,백병천,이원준 國立 麗水大學校 環境問題硏究所 2002 環境硏究論文集 Vol.5 No.-

Analysis items of this study were 1,1-dichloroethene, dichloromethane, chloroform, 1,2-dichloroethane, 1,1,1-trichloroethane, benzene, carbontertrachloride, toluene, ethylbenz ene, m,p-xylene, styrene, o-xylene. Equipment of analysis was purge & Trap/HP-6890GC/5973MSD, GC operating condition was carrier gas 99.999% Helium-0.7㎖/min, Trap meterial Tenax/SG?Charcoal, Column HP-PONA(Crosslinked Methyl Siloxane, 50m×0.2mm×0.5㎛), Oven program 35℃(10min)-4℃/min 150℃-1 5℃/min 200℃(5min), Aux 280℃, MS Source 230℃, MS Quad 150℃ Result of RSD% measurement was chloroform 9.37%, 1,2-dichloroethane 5.79%, 1,1,1-trich loroethane 12.56%, benzene 4.31%, carbon tetrachloride 15.35%, toluene 3.89%, ethylben zene 5.69%, m,p-xylene 5.65, styrene 4.02%, o-xylene 2.94%. Result of analysis showed that 1,1,1-trichloroethane, carbontetrachloride, dichloromethane were not detected, 1,1-dichloethane was detected level of 0.19ppb, 0.26ppb in 1st sampling point 6, 7, 1,2-dichloromethane 0~7.25ppb, benzene 0~0.9ppb, toluene 0/11~1/79ppb, ethyelbenzne 0~2.15ppb, m,p-xylene 0~2.32ppb, styrene 0~0.8ppb, o-xylene 0~0.68ppb.

영상 데이타 베이스 시스템 설계 및 구현

金炳天,金三根 안성산업대학교 1991 論文集 Vol.23 No.-

This paper presents how to design the integrated image database system for image and relational database since past years. The image database management system that maintains both image and signal data is stored in logical image, which consists of the set of image objects, and relational table. Since database and image processing techniques have been recently developed, and memory and device technology have been considerably advanced, there are fast increasing the requirement that integrates both image and database. This paper, therefore, proposes the image database management system that introduces query for user friendliness. The purpose of this paper is to is to focus on concernment for image database.

영상정보저장 및 검색시스템

金炳天,金奉權 안성산업대학교 1991 論文集 Vol.23 No.-

오늘날 컴퓨터의 주된 사용은 많은 양의 데이터를 적절히 분류하여 저장하고 이들로부터 정보를 얻어내는 데 있다. 특히, 기호자료(symbolic data) 뿐만 아니라 영상자료(Image data)에 대한 처리가 필수적으로 요구되고 있는 시점에서 영상정보 저장 및 검색 시스템에 대한 중요성은 고조되고 있다. 그러므로 영상정보를 다루기 위한 시스템은 매우 중요한 것으로 인식된다. 본 논문에서는 영상정보의 저장 및 검색 기법에 대해 논하며, 영상정보 저장 및 검색 시스템을 설계하고 구현한 결과와 특징을 소개한다. Nowadays the main usage of a computer is to store and retrieve a large set of data. Especially there increases a need for a computer to handle image data as well as symbolic data. Thus, the role of image information system becomes very important. This paper dicusses key issues that one should consider when designing image information system. And then this paper describes main properties of our Image Information Store and Retrieval system.

ID-GC/MS에 의한 쌀 중의 잔류농약 인증표준물질

김유곤,김달호,백병천,이우범 國立 麗水大學校 환경문제硏究所 2001 環境硏究論文集 Vol.4 No.-

The CRM used in evaluation of effectiveness, calibration or analysis equipment when you analyse in material of rice powder or similar matrix. Analytical items were γ-HCH, p,p'-DDE, endosulfan-2, samples of achieved pertreatment analized each component indivisually. Control mode of MS used selected ion monitering(SIM). GC is 6890GC of Agilent Technology company and MS is JMS 700 of Jeol company. MS operating condition was Electron impact ionization with 70eV. 300A, GC operating condition was Column : Rtx-5MS 30m*0.25m ID*0.25um, Oven Temp 90℃(3min)-20℃/min-280℃(2min), Injection port 250℃, splitless, Carrier Gas He with 1mL/min. Water contents was 12.534% and dry mass correction factor 1.143. CRM certified values of the experiment result were p,p'-DDE 0.165±0.011,mg/kg, γ-HCH 0.0129±0.0011mg/kg, endosulfan-2 0.0216±0.0027mg/kg. The numbers following the symbol ± are the numerical values of expanded uncertainties, U=ku_(c) of measurement values preceding the symbol. The level of confidence for the expanded uncertainties are 96% with k=2.

급성 및 만성 간질환에서 C형 간염바이러스 항체(anti-HCV)양성률

김삼용,성자원,김병호,이기천,허승식,길준영,정현용,이헌영,김영건 충남대학교 의과대학 지역사회의학연구소 1992 충남의대잡지 Vol.19 No.2

The prevalence of antibody against hepatitis C virus (anti-HCV) was investigated in 331 patients with various liver diseases from April 1992 to September 1992. The presence of anti-HCV was detected by Lucky HCD EIA test in 331 cases and by (Ortho HCV Antibody ELISA test 148 patients) The results are summarized as follows: 1. Overall, antibody to HCV(anti-HCV) was positive in 37(11%) of 331 patients with various liver diseases. 2. 16(11%) of 144 patients with chronic hepatitis, 2(5%) of 37 patients with alcoholic liver disease, 17(22%) of 76 patients with liver cirrhosis and 2(5%) of 38 HBsAg carriers were positive for anti-HCV.None of 12 patients with acute hepatitis, 11 patients with drug induced hepatitis and 13 patients with hepatocellular carcinoma was anti-HCV positive. 3. HBsAg positivity in patients who had anti-HCV was 24%(9/37). 4. A positive correlation was found between Lucky HCD and Ortho HCV test. Of 128 Lucky HCD negative cases, 124 cases were negative for Ortho HCV ELISA and 4 cases were positive for Ortho HCV ELISA Of 20 Lucky HCD positive cases, 11 cases were positive for Ortho HCV ELISA and 9 cases were negative for Ortho HCV ELISA. These results suggest that hepatitis C virus has an important etiologic role in HBsAg negative chronic hepatitis and liver cirrhosis in Korea. The diagnostic value of Lucky HCD EIA test may be slightly better or equivalent to Ortho HCV ELISA test in the diagnosis of Hepatitis C virus infection.

탄화수소를 환원제로 하는 배연 탈질공정에서 금속이온교환된 ZSM-5 촉매들의 촉매활성 비교연구

김재천,한상현,신병선,정석진 경희대학교 산학협력기술연구원 1998 산학협력기술연구논문집 Vol.4 No.-

In this study, in order to make up its drawbacks in the Cu-ZSM-5 catalytic system, some of transition metals or alkaline earth metals were cocation-exchanged in Cu-ZSM-5. Among various cocation-ion-exchanged XSM-5 catalysts, Mg/Cu-ZSM-5 was found to be the most active and durable in NOx reduction even with high oxygen content as well as in the presence of water vapor. The role of Mg in ZSM-5 is supposed to prevent the dealumination of aluminium ions the in supercage even at harsh hydro-thermal conditions, and also it seems to stabilize the Cu ions in the structure. In order to prepare commercially available catalysts, Mg/Cu-ZSM-5 catalysts were wash-coated on the surface of honeycomb type monolith, and tested in terms of catalytic activities. As a results, it was found that the catalyst prepared by the wash-coating showed satisfactorily high NOx conversion for the practical in the SCR process.

내시경으로 확인된 상부소화관 용종의 임상적 고찰

김영건,김병호,성자원,이기천,허승식,이종선,정현용,이헌영 충남대학교 의과대학 지역사회의학연구소 1991 충남의대잡지 Vol.18 No.2

From January 1987 to October 1991, we performed 14,333 cases of upper gastrointestinal endoscopy and diagnosed 527 cases with U.G.I polyp. We assesed these 527 cases and obtained following results: 1) The overall incidence of U.G.I. polyps was 3.6%, and there was no sexual difference. The peak incidence was in 6th decades(32.4%). 2) The U.G.I. polyps were located chiefly at stomach(415 cases, 78.7%), among which antrum occupied antrum 43.5%, body 24.0% and funds 5.1%. And the others were esophagus(6.5%) and duodenum(12.3%). 3) The size of U.G.I. polyp was below 1cm in 72.3%, from 1cm to 1.9cm in 20.7% and above 2cm in 7.0%. According to Yamada' classification, type Ⅰ, Ⅱ, Ⅲ and Ⅳ was 31.9%, 51.3%, 13.7% and 3.0%. 4) Histological nature of U.I.G. polyp were hyperplastic polyp(85.8%), adenomatous polyps(9.3%), carcinomatous polyps(3.3%) and etc. The size of neoplastic polyp such as adenomatous polyps(mean 1.0±0.7cm) and carcinomatous polyps(niean 2.0±1.8) were larger man hyperplastic polyp(mean 0.6±0.4) (p<0.05) 5) The gastric polyps were associated with peptic ulcer(7.5%), gastric cancer(3.2%), other malignancy(3.5%), hepatobiliary disease(5.5%), post subtotal gastrectomy(5.5%). And others(75%) werenot associated with specific disease.

내시경으로 진단된 소화성 궤양의 임상적 고찰

김영건,육은주,김성걸,임의혁,성자원,김병호,허승식,이기천,정현용,이헌영 충남대학교 의과대학 지역사회의학연구소 1993 충남의대잡지 Vol.20 No.2

A clinical analysis was performed of 3055 pateints with peptic ulcer who were diagnosed with gastroduodenoscopy, in Hospital of Chungnam National University College of Medicine from July 1988 to May 1993. 1) During the period 1988-1993, The proportion of gastric ulcer among peptic ulcer decreased from 47.8% to 42.8%, but that of duodenal ulcer increased from 36.8% to 39.6%. 2) Of the 3055 cases, the number of patients with esophageal ulcer was 98(3.2%), with gastric ulcer 1407(41.6%), with. duodenal ulcer 1104(36.1%), with channel ulcer 149(4.9%), and with combind ulcer 297(9.7%). 3) We observed a peak incidence of peptic ulcer in the 50-69age group, gastric ulcer in the 5069age, duodenal ulcer in the 40-59age group. The ratio of male to female was 3.6 : 1 in peptic ulcer, 4.4 : 1 in gastric ulcer, 3.0 : 1 in duodenal ulcer. 4) The common site was angle in gastric ulcer, and bulb in duodenal ulcer. 5) The active stage was 39.4% of gastric ulcer, and 37.4% of duodenal ulcer, the healing stage was 34.2% of gastric ulcer, and 17.9% of duodenal ulcer, and the scar stage of gastric ulcer was 26.4%, and duodenal ulcer was 44.7%. 6) The size of ulcer was less than 1Cm in 66.7% of gastric ulcer, and in 75.5% of duodenal ulcer, the size of ulcer was greater than 2Cm in 13.2% of gastric ulcer, and in 6.5% of duodenal ulcer. 7) The frequency of multiple ulcer was 29.9% in gastric ulcer, and 16.5% in duodenal ulcer.

어린이의 식이습관과 치아우식발생과의 상관관계에 관한 연구

김재곤,전철완,이두철,백병주 대한소아치과학회 2001 大韓小兒齒科學會誌 Vol.28 No.2

본 연구는 치아우식 발생과 식이습관과의 상관관계를 알아보기 위하여 전주시내 소재 유치원에 다니는 남아 143명과 여아 124명을 대상으로 유치의 우식경험지수를 조사하고, 어머니로부터 설문조사를 통하여 어머니의 직업유무, 수유경험 및 어린이의 식품기호도 등을 조사한 후 이상의 자료를 분석하였으며, 본 연구에서 나타난 결과들을 중심으로 다음과 같은 결론을 얻었다. 전체 어린이의 유치 우식경험지수는 2.92±1.05이였으며 여아(3.40±1.46)가 남아(2.51±0.97) 보다 다소 높은 우식경험지수를 나타냈으나, 남녀간의 유의한 차이는 나타나지 않았으며(P>0.05), 연령에 따른 유치의 우식경험지수를 비교한 결과, 나이가 증가할수록 높아지는 양상을 보였으며, 3세와 4세에 비해 5세와 6세에서 각각 높은 우식경험지수를 나타냈다(P<0.05). 각 식품군에 대한 기호도에서 남아는 과실류를, 여아는 해조류를 가장 좋아하였으며, 해조류를 제외한 다른 식품군에서 남녀별 유의한 차이를 나타내지 않았으며(P>0.07), 조사 식품군에 대한 어린이의 기호도와 관련한 유치 우식경험지수를 비교한 결과. 당류(r=0.3854, P<005), 유류(r=0.4328, P<0.05), 음료(r=0.2586, P<0.05)에서는 유의성이 인정되었으나, 다른 식품군에서는 유의한 상관성이 인정되지 않았다(P>0.05). The aim of the present study was to analyze relationship between dietary habits and dental caries experience inpreschool children. All 143 boys and 124 girls living in a chonju city were investigated dmf index by dentists through oral examination and dietary habit by children's mothers through questionaires such as infant diets and food preferences. The statistical analysis were performed to evaluate whether variations in dietary habits are related to dental caries experience. The obtained results were as follows; 1. The average dmf index scores of all children were examined 2.92±1.05. The girls had higher than the boys, but no significant differences between the genders were seen the을 index(P>0.05). 2. The higher were their age of children, the higher dmf index was investigated. The dmf index of 5 and 6-yr old childrens was higher than that in 3 and 4-yr old children(P<0.05). 3. No sigificant difference was found between the present of mother's occupation (P>0.05) and type of infant dietary habits(P>0.05). 4. The fruits and sea weeds were showed high degree of preference and fats and vegetables were showed low degree generally. Among 13 food groups, there was no significant difference between boys and girls except for sea weeds(P>0.05). 5. Among 13 food groups, the을 index was positively associated with sugars(r=0.3854, P<0.05), dairy products(r=0.4328, P<0.05) and soft drinks(r=0.2586, P<0.05), and negatively associated with other food groups.

.Pseudomonas stutzeri 감염에 의한 맥락총염에서 초래된 포착성 측뇌실 확장 1예

김남곤,권오영,박기종,최낙천,임병훈 대한신경과학회 1997 대한신경과학회지 Vol.15 No.2