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Electrochemical synthesis and corrosion behaviour of poly (pyrrole-co-o-anisidine-co-o-toluidine)
Süleyman Yalçınkaya,Tunç Tüken,Birgül Yazıcı,Mehmet Erbil 한국물리학회 2010 Current Applied Physics Vol.10 No.3
In this study, a ter-polymer film of pyrrole, o-anisidine and o-toluidine has been electrochemically synthesized on low carbon steel. The synthesis solution was aqueous oxalic acid containing 2:1:1 monomer feed ratio between pyrrole, o-anisidine and o-toluidine, respectively. The characterization of synthesized ter-polymer film was realized with help of UV–Vis absorption, Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM) and differential scanning calorimetry (DSC) techniques. The stability of this ter-polymer film as a coating material has also been investigated on steel, in 3.5%NaCl solution. Under such severe conditions, the ter-polymer film was found to exhibit low permeability against water ingress. It was able to exhibit protective coating behavior on steel, even after 72 h exposure time. The DSC results revealed that the ter-polymer film had better thermal stability with respect to single polypyrrole film. The synthesized ter-polymer film was completely different in aspect of morphology,stability and other structural properties when compared to single polypyrrole film. This highly stable and extremely thin (0.80 ㎛) film can find application for various purposes (anticorrosive, electrocatalytic,etc.), at where the stability of polypyrrole like films constitutes a drawback.