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Photo-sensitivity of large area physical vapor deposited mono and bilayer MoS2
Wang Baoming,Muratore Christopher,Voevodin Andrey A,Haque Md Amanul 나노기술연구협의회 2014 Nano Convergence Vol.1 No.22
We present photosensitivity in large area physical vapour deposited mono and bi-layer MoS 2 films. Photo-voltaic effect was observed in single layer MoS 2 without any apparent rectifying junctions, making device fabrication straightforward. For bi-layers, no such effect was present, suggesting strong size effect in light-matter interaction. The photo-voltaic effect was observed to highly direction dependent in the film plane, which suggests that the oblique deposition configuration plays a key role in developing the rectifying potential gradient. To the best of our knowledge, this is the first report of any large area and transfer free MoS 2 photo device with performance comparable to their exfoliated counterparts.
Yuan Zhang,Wenwei Jiang,Yongsheng Ren,Baoming Wang,Yong Liu,Quanxian Hua,Jianwei Tang 한국화학공학회 2020 Korean Journal of Chemical Engineering Vol.37 No.3
2-chloro-4,6-dinitroresorcinol (CDNR) is detrimental to the environment and human health owing to its high toxicity and poor biodegradability. To demonstrate the feasibility of photocatalytic degradation of CDNR from industrial salty wastewater by borosilicate glass supported TiO2 under UV light irradiation, borosilicate glass supported TiO2 was prepared successfully by a novel sol-gel route via dip-coating method and characterized by XRD, SEM, FTIR and XPS analysis. The results showed that TiO2 catalyst has the anatase phase structure with crystallite size of 11.5 nm and coats uniformly on the borosilicate glass. Also, the effects of reaction time, pH value, TiO2 dosage, CDNR concentration, and Cl on the degradation efficiency of CDNR were investigated. The results indicated that at pH 2, reaction time 3.5 h, CDNR concentration 10mg/L, NaCl concentration 5.85% (w/w) and TiO2 dosage 1.0 g/L, 97.7% of CDNR was degraded in the presence of Cl, this corresponded to a rate constant of 1.05 h1, illustrating the feasibility of photocatalytic degradation process. This contribution provides a basic investigation regarding the potential application of borosilicate glass supported TiO2.