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Sakthivel, R.,Karthick, S.A.,Kaviarasan, B.,Lim, Yongdo Elsevier 2017 Applied Mathematics and Computation Vol.311 No.-
<P><B>Abstract</B></P> <P>This paper aims to solve the reliable state estimation problem of an uncertain switched neutral system subject to nonlinear actuator faults and time-varying delay by using sampled-data approach. To be precise, the well-known Luenberger estimator is constructed to determine the immeasurable states of the addressed system and a general actuator fault model is employed to describe the nonlinearities encountering in the control design. After that, by defining an error variable, the corresponding estimation error system is formulated. By the virtue of Lyapunov–Krasovskii stability theory and average dwell-time method, a new delay-dependent sufficient criterion is established to guarantee the existence of the desired estimator and sampled-data gains and subsequently, the explicit expression of those gains is presented by means of the solution to a set of linear matrix inequalities. Moreover, two numerical examples are given to show the efficiency of the proposed estimator design schemes, where it is shown that the estimator gains can ensure the exponential stability of the considered switched neutral systems.</P>
Durability performance of CNT and nanosilica admixed cement mortar
Lee, Han Seung,Balasubramanian, B.,Gopalakrishna, G.V.T.,Kwon, Seung-Jun,Karthick, S.P.,Saraswathy, V. Elsevier 2018 Construction and Building Materials Vol.159 No.-
<P><B>Abstract</B></P> <P>In the recent years, development and use of nanomaterials are gaining importance in the construction industries due to the advancement of science and technology. In the present investigation, nanosilica (NS) was synthesized from rice husk ash and characterized using XRD, Particle size analysis and SEM techniques. 1% NS by weight was used in cement mortar along with carbon nano tube (0.01%–0.07%) as a cement replacement materials and rock dust (RD) was used as a replacement for river sand. Five different mix combinations were formulated. Polycarboxylate based water reducing admixture was used for improving the workability of the mix. All the combination of mixes derived were subjected to compression, split tensile test, and durability studies such as sorptivity, water absorption, and chloride penetration test. Potentiodynamic polarization study was carried out to understand the corrosion performance of the composite cement mortar. SEM and XRD studies were carried out for the hydrated products of the composite cement mortar. The results showed that NS and CNT increased the compressive strength by 12%–76% and enhanced the corrosion resistance properties than the control.</P> <P><B>Highlights</B></P> <P> <UL> <LI> The synergistic effect of NS with CNT composite cement mortar was investigated. </LI> <LI> Strength and durability properties were enhanced by the addition of NS and CNT. </LI> <LI> Polarization study revealed that the corrosion resistance was enhanced. </LI> <LI> SEM and XRD confirmed that NS and CNT accelerated the hydration process and resulted in denser microstructure formation. </LI> </UL> </P>
Maruthamuthu, S,Chandrasekaran, J,Manoharan, D,Karthick, SN,Kim, Hee‐,Je,Saravanakumar, B John Wiley Sons, Ltd 2016 Polymer international Vol.65 No.5
<P><B>Abstract</B></P><P>Nanocolloidal polypyrrole (PPy):poly(styrene sulfonate) (PSS) particles were synthesized by chemical oxidative polymerization using 15 wt% of PSS. The highly processable polymer composite (PPy:PSS) was spin‐coated at 4000 rpm on fluorine‐doped tin oxide glass and subsequently employed as a counter electrode (CE) for dye‐sensitized solar cells (DSCs). PPy:PSS multilayer (one, three, five) CEs were treated with CuBr<SUB>2</SUB> salt, which enhances the efficiency of the DSCs. Optical studies reveal that a bulkier counterion hinders interchain interactions of PPy which on salt treatment shows a moderate redshift in absorption maxima. Salt‐treated PPy:PSS films exhibit lower charge transfer resistance, higher surface roughness and better catalytic performance for the reduction of I<SUB>3</SUB><SUP>−</SUP>, when compared with untreated films. The improved catalytic performance of salt‐treated PPy:PSS multilayer films is attributed to charge screening and conformational change of PPy, along with the removal of excess PSS. Under standard AM 1.5 sunlight illumination, salt treatment is shown to boost the efficiency of multilayer PPy:PSS composite film‐based DSCs, leading to enhanced power conversion efficiency of 6.18, 6.33 and 6.37% for one, three and five layers, respectively. These values are significantly higher (<I>ca</I> 50%) than those for corresponding devices without CuBr<SUB>2</SUB> salt treatment (3.48, 2.90 and 2.01%, respectively). © 2016 Society of Chemical Industry</P>
Effect of medium coarse aggregate on fracture properties of ultra high strength concrete
B. Karthick,M.P. Muthuraj 국제구조공학회 2021 Structural Engineering and Mechanics, An Int'l Jou Vol.77 No.1
Ultra high strength concrete (UHSC) originally proposed by Richards and Cheyrezy (1995) composed of cement, silica fume, quartz sand, quartz powder, steel fibers, superplasticizer etc. Later, other ingredients such as fly ash, GGBS, metakaoline, copper slag, fine aggregate of different sizes have been added to original UHSC. In the present investigation, the combined effect of coarse aggregate (6mm – 10mm) and steel fibers (0.50%, 1.0% and 1.5%) has been studied on UHSC mixes to evaluate mechanical and fracture properties. Compressive strength, split tensile strength and modulus of elasticity were determined for the three UHSC mixes. Size dependent fracture energy was evaluated by using RILEM work of fracture and size independent fracture energy was evaluated by using (i) RILEM work of fracture with tail correction to load – deflection plot (ii) boundary effect method. The constitutive relationship between the residual stress carrying capacity (σ) and the corresponding crack opening (w) has been constructed in an inverse manner based on the concept of a non-linear hinge from the load-crack mouth opening plots of notched three-point bend beams. It was found that (i) the size independent fracture energy obtained by using above two approaches yielded similar value and (ii) tensile stress increases with the increase of % of fibers. These two fracture properties will be very much useful for the analysis of cracked concrete structural components.
B. Karthick,T. Meyyappan 한국전산응용수학회 2023 Journal of applied mathematics & informatics Vol.41 No.5
Social media platforms have become an integral part of our daily lives, and they generate vast amounts of data that can be analyzed for various purposes. However, the quality of the data obtained from social media is often questionable due to factors such as noise, bias, and incompleteness. Enhancing data quality is crucial to ensure the reliability and validity of the results obtained from such data. This paper proposes an enhanced decision-making framework based on Business Decision Management Systems (BDMS) that addresses these challenges by incorporating a data quality enhancement component. The framework includes a backtracking method to improve plan failures and risk-taking abilities and a steep optimized strategy to enhance training plan and resource management, all of which contribute to improving the quality of the data. We examine the efficacy of the proposed framework through research data, which provides evidence of its ability to increase the level of effectiveness and performance by enhancing data quality. Additionally, we demonstrate the reliability of the proposed framework through simulation analysis, which includes true positive analysis, performance analysis, error analysis, and accuracy analysis. This research contributes to the field of business intelligence by providing a framework that addresses critical data quality challenges faced by organizations in decision-making environments.
B. Balamuralitharan,Suresh Kannan Balasingam,S. N. Karthick,Ananthakumar Ramadoss,Manab Kundu,박진수,조인호,프라바카르,전용석,김희제 한국공업화학회 2019 Journal of Industrial and Engineering Chemistry Vol.71 No.-
Iron pyrite (FeS2) is an interesting mineral in the transition metal dichalcogenide group due to its highabundance in the earth’s crust which can be used for various electrochemical energy storage applications,such as batteries and supercapacitors; however, it suffers from low rate capability and poor cycleperformance, which hampers its use from large-scale commercial applications. In the present study, irondisulfide microspheres anchored onto a reduced graphene oxide matrix (rGO-FeS2 hybrid) were grownusing a superficial hydrothermal method. For comparison, rGO-free iron disulfide material wassynthesized under the same hydrothermal conditions, and uniformly distributed FeS2 micro-sizeflowerswere formed. The energy storage capacity of both electroactive materials (FeS2 and rGO-FeS2 hybridmaterial) was tested for supercapacitor applications in a symmetric cell configuration. The pristine FeS2microflower electrode exhibited an areal capacitance of 70.98 mF cm 2 at 5 mV s 1. On the other hand,the rGO-FeS2 hybrid microsphere electrode exhibited an enhanced areal capacitance of 112.41 mF cm 2 atthe same scan rate with an excellent capacitance retention of 90% over 10,000 cycles. The improvedelectrochemical performance of the rGO-FeS2 hybrid material is due mainly to its improved electricalconductivity, high surface area indicating an enhanced electron, and ion transfer mechanism. This studysuggests that the rGO-FeS2 hybrid electrode material has potential applications in energy storage devices.
Selvam, S.,Balamuralitharan, B.,Jegatheeswaran, S.,Kim, M. Y.,Karthick, S. N.,AnandhaRaj, J.,Boomi, P.,Sundrarajan, M.,Prabakar, K.,Kim, H. J. Royal Society of Chemistry 2017 Journal of Materials Chemistry A Vol.5 No.4
<P>Electrolyte-imprinted and copper crosslinked hybrid flexible electrodes have been considered as long-term stability supercapacitors. Graphene oxide, chitosan and copper (copper chloride) were crosslinked under ionic liquid medium using a hydrothermal technique. The fabricated flexible supercapacitor exhibits a maximum 356 F g(-1) specific capacitance and possesses extreme cyclic stability up to 200 000 cycles.</P>
Selvam, S.,Balamuralitharan, B.,Karthick, S. N.,Hemalatha, K. V.,Prabakar, K.,Kim, Hee-Je The Royal Society of Chemistry 2016 Analytical methods Vol.8 No.44
<▼1><▼1><P>A self-powered supercapacitor based on a caffeine sensor electrode has been developed using an electrochemically deposited rGO/β-CD/MnO2 ternary composite with ionic liquid assistance.</P></▼1><▼2><P>A self-powered supercapacitor based on a caffeine sensor electrode has been developed using an electrochemically deposited rGO/β-CD/MnO2 ternary composite with ionic liquid assistance. This typical composite electrode was prepared from electrochemically reduced e-rGO followed by the addition of β-cyclodextrin and MnO2 from Mn(CH3COOH)2·4H2O on FTO surfaces. The composite material is indexed to the corresponding crystalline phase of MnO2 in the XRD investigation and Mn 3p, Mn 2p, C 1s, and O 1s signals were identified from XPS analysis. The cyclic voltammetry study reveals that the potential of the caffeine samples and the square wave voltammetry peak currents indicate an increasing trend for caffeine oxidation. The sensor expressed a sensitivity of 0.187 μA cm<SUP>2</SUP> μM<SUP>−1</SUP> with a linear range of 10–550 μM (<I>n</I> = 3.12). The corresponding supercapacitor also exhibited a specific capacitance of 352 F g<SUP>−1</SUP> and it showed a very good life time from a long term cyclic test. The proposed ternary composite electrodes may be suitable electrodes for self-powered sensor devices.</P></▼2></▼1>
Selvam, S.,Balamuralitharan, B.,Karthick, S. N.,Savariraj, A. Dennyson,Hemalatha, K. V.,Kim, Soo-Kyoung,Kim, Hee-Je The Royal Society of Chemistry 2015 Journal of Materials Chemistry A Vol.3 No.19
<▼1><P>A novel sulfated β-cyclodextrin/PVP/MnCO3 composite has been synthesized for a parallel-connected supercapacitor and dye-sensitized solar cell (counter electrode).</P></▼1><▼2><P>A novel sulfated β-cyclodextrin/PVP/MnCO3 composite has been synthesized for a parallel-connected supercapacitor and dye-sensitized solar cell (counter electrode). β-Cyclodextrin has sulfonated, thermally cross-linked with PVP, and incorporated with MnCO3 nanoparticles. The composite electrode exhibited 202.6 F g<SUP>−1</SUP> capacitance, 197.96 W h kg<SUP>−1</SUP> energy density, 5.57% <I>η</I> (DSSC) and 70% performance up to 200 °C with a [BMI][TFSI] electrolyte.</P></▼2>