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        Emerging chemo-biocatalytic routes for valorization of major greenhouse gases (GHG) into industrial products: A comprehensive review

        Kriti Sharma,Young-Kwon Park,Ashok Kumar Nadda,Priya Banerjee,Pradeep Singh,Pankaj Raizada,Fawzi Banat,G. Bharath,Sang Mun Jeong,Su Shiung Lam 한국공업화학회 2022 Journal of Industrial and Engineering Chemistry Vol.109 No.-

        Climate change is one of the major global concerns of 21st century, and the release of excessive greenhousegases (GHG) is the foremost reason behind. It has become imperative to either capture excessiveemission of GHG into the atmosphere or to develop advanced and efficient technologies for preventingfurther increase in its atmospheric concentration. Algal and microbial enzymes have been found to beeffective in catalyzing the conversion of GHG to value-added products like biofuels, chemicals, polymers,biogas, and bioelectricity etc. However, these enzymes yield better catalytic activities when applied incombination with nano-materials having similar prowess for capturing and converting GHG. Replacingconventional chemical production through GHG capture and utilization affects emission of the samethroughout the production chain (i.e., from cradle-to-gate). Herein, we analyze the technical potentialof hybrid chemo-biocatalytic processes for GHG capture and their utilization to produce valuable industrialcompounds. The study addresses the biosynthesis as well as genetic and metabolic engineering ofdifferent microbial enzymes for GHG sequestration and conversion. It also reviews recent literature ofusing different advanced materials for immobilization of enzymes and their subsequent application forGHG sequestration and conversion to valuable products.

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