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Roozbeh Hoseinzadeh Hesas,Arash Arami-Niya,Wan Mohd Ashri Wan Daud,J.N. Sahu 한국공업화학회 2015 Journal of Industrial and Engineering Chemistry Vol.24 No.-
Activated carbon (AC) was prepared from oil palm shell using different ratios of KOH as an activation agent and various microwave irradiation powers. To study the effects of physical agents, the impregnated precursors were activated under a flow of CO2 or N2. Maximum BET surface areas of 1196 and 1630 m2/g were achieved in the presence of CO2 and N2, respectively. The textural properties of the samples with the highest surface areas were investigated using ultimate and proximate analyses, SEM and FTIR. The CO2 adsorption results suggest that the ACs are promising adsorbents for gas separation or storage applications.
Modification of Activated Carbon Using Nitration Followed by Reduction for Carbon Dioxide Capture
Mohammad Saleh Shafeeyan,Amirhossein Houshmand,Arash Arami-Niya,Hosain Razaghizadeh,Wan Mohd Ashri Wan Daud 대한화학회 2015 Bulletin of the Korean Chemical Society Vol.36 No.2
Activated carbon (AC) samples were modified using nitration followed by reduction to enhance their CO2 adsorption capacities. Besides characterization of the samples, investigation of CO2 capture performance was conducted by CO2 isothermal adsorption, temperature-programmed (TP) CO2 adsorption, cyclic CO2 adsorption–desorption, and dynamic CO2 adsorption tests. Almost all modified samples showed a rise in the amount of CO2 adsorbed when the comparison is made in unit surface area. On the other hand, some of the samples displayed a capacity superior to that of the parent material when compared in mass unit, especially at elevated temperatures. Despite ~65% decrease in the surface area, TP-CO2 adsorption of the best samples exhibited increases of ~10 and 70% in CO2 capture capacity at 30 and 100 °C, respectively.