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Tao Wang,Aili Yan,Longgang Zhong,Sheng Wang 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2017 NANO Vol.12 No.10
The main issue limiting the widespread application of superhydrophobic coatings is their low surface robustness, which is closely related to surface roughness on the micro- or nanoscale, and is mechanically weak and easily gets abraded. This work uses Te nanowires as templates to support a carbon layer substrate for the growth of titanium dioxide nanoparticles; this forms hierarchical structures (Te@C-TiO2 nanocomposites). Modification with 1H, 1H, 2H, 2H - perfluoroalkyltriethoxysilane created a free-standing superhydrophobic coating. The optimal preparation conditions for the coating were identified after a systematic investigation of the reaction time of the carbon precursor and concentration of TiOSO4. The best anti-wetting performance was attained with 200 nm diameter Te@C and 15mL concentration of TiOSO4. Furthermore, due to their free-standing performance, the nanocomposites were easily loaded onto a polyester fabric to generate a robust superhydrophobic fabric. This fabric shows excellent mechanical durability and strong resistance to knife scratching, sandpaper abrasion, washing, as well as exposure to acid and alkali solutions. Moreover, the robust fabric is able to separate oil/water mixtures with high separation efficiency.
Huihui Cao,Yanhua Yan,Lei Wang,Lixue Dong,Xueliang Pang,Sining Tang,Aijun Li,Aili Xiang,Litian Zhang,Baiqin Zheng 한국축산식품학회 2021 한국축산식품학회지 Vol.41 No.3
Raw milk is a nature media of microbiota that access milk from various sources, which constitutes a challenge in dairy production. This study characterizes the relationship between the raw milk quality and the bacteria diversity at different sampling sites in dairy farms, aiming to provide a strong scientific basis for good hygienic practices and optimized procedure in milk production. High-throughput sequencing of 16S rRNA V3-V4 region was used to analyze the components, abundance and diversity of 48 bacterial population sampled from 8 different sites in dairy farm: pre-sterilized cow’s teats (C1), post-sterilized cow’s teats (C2), milking cluster (E), milk in storage tank (M1), transport vehicle (M2), storage equipment (E2), cow’s dung samples (F) and drinking water (W). Firmicutes account for predominantly 32.36% (C1), 44.62% (C2), 44.71% (E), 41.10% (M1), 45.08% (M2), 53.38% (F) of all annotated phyla. Proteobacteria accounts for 81.79% in W group and Actinobacteria 56.43% in E2 group. At the genus level, Acinetobacter was the most abundant genus that causes bovine mastitis, Acinetobacter and Arthrobacter were dominant in C1, C2, and E groups, Kocuria in E2 group and Arcobacter in W group. E, C1, and C2 group have very similar bacterial composition, and M1 and M2 demonstrated similar composition, indicating that the milking cluster was polluted by the environment or contact with cow udders. Bacterial population composition in different sampling sites identified by NGS reveals a correlation between the bacteria communities of raw milk production chain and the quality of raw milk.
Huasheng Lu,Hengbo Yin,Aili Wang,Jun Shen,Xiaobo Yan,Yumin Liu,Changhua Zhang 한국화학공학회 2014 Korean Journal of Chemical Engineering Vol.31 No.1
Diethyl 3,4-ethylenedioxythiophene-2,5-dicarboxylate was efficiently synthesized via the O-alkylation of disodium salt of diethyl 3,4-dihydroxythiophene-2,5-dicarboxylate with 1,2-dichloroethane over ionic type phase transfer catalysts, such as tetrabutyl ammonium bromide and benzyltriethyl ammonium chloride. The ionic type phase transfer catalysts showed higher catalytic activities than the nonionic type phase transfer catalysts, such as triethylamine,pyridine, 18-crown-6, and polyethylene glycol 400/600, in the O-alkylation reaction. The conversion of the disodium salt of more than 97% and the selectivity of diethyl 3,4-ethylenedioxythiophene-2,5-dicarboxylate of more than 98%were achieved when the O-alkylation reaction was synergistically catalyzed by tetrabutyl ammonium bromide and potassium iodide.