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산소희박환경에서 과산화수소를 이용한 디젤개질 가능성 탐구
한광우 ( Gwangwoo Han ),배민석 ( Minseok Bae ),배중면 ( Joongmyeon Bae ) 한국화학공학회 2015 Korean Chemical Engineering Research(HWAHAK KONGHA Vol.53 No.5
잠수함 및 수중무인체계 등의 산소희박환경에서 연료전지를 통한 효과적인 전력생산을 위해서는 높은 수소저장밀도를 갖는 수소공급원이 필요하다. 디젤연료는 액체연료로서 저장 및 공급이 용이하며, 연료전지의 연료가 되는 수소의 단위질량 및 단위부피당 저장밀도가 높은 장점을 갖고 있다. 이러한 디젤연료의 장점을 기반으로 본 연구에서는 산소희박환경에서 수소생산을 위해 디젤연료의 개질반응을 이용하였으며, 산화제로 단위부피당 산소 저장밀도가 높고 액상으로 보관이 용이한 과산화수소 수용액을 기존의 산화제인 물과 산소의 대체산화제로 이용하는 방법을 제안하였다. 과산화수소 수용액의 디젤개질 산화제로써의 특성을 파악하기 위해 물, 공기 산화제와의 비교실험을 진행하였으며, 기존의 산화제와 디젤 개질반응 시 동일한 특성을 갖는 것을 실험적으로 확인하였다. 또한 상용디젤을 연료로 온도 및 과산화수소 수용액의 농도에 따른 개질성능을 평가하였으며, 49시간의 가속 열화실험을 통하여 디젤, 과산화수소 수용액을 이용한 수소생산의 가능성을 확인하였다. For effective power generation with fuel cells in low-oxygen environments such as submarines and unmanned underwater vehicles, a hydrogen source which has a high hydrogen storage density is required. Diesel fuel is easy to storage and supply due to its liquid phase and it has a high density per unit volume and unit mass of hydrogen that required for driving the fuel cells. In this paper, diesel fuel was selected as a hydrogen source for driving the fuel cell in oxygen lean environments. In addition, the aqueous hydrogen peroxide solution was suggested as an alternative oxidant for hydrogen production through the diesel reforming reaction because of its high oxygen density and liquid phase which makes it easy to storage. In order to determine the characteristics of hydrogen peroxide as an oxidant of diesel reforming, comparative experiments were conducted and it was found that hydrogen peroxide solution has the same characteristics when reformed with oxidants of both steam and oxygen. Moreover, the commercial diesel reforming performances were analyzed according to the reaction temperature and concentration of aqueous hydrogen peroxide solution. Then, through the 49 hours accelerated degradation tests, the possibility of hydrogen production via diesel and aqueous hydrogen peroxide solution was confirmed.
한광우(Gwangwoo Han),홍종은(Jong-Eun Hong),이왕제(Wang-Je Lee),이경호(Kyoung-Ho Lee),주홍진(Hong-Jin Joo),안영섭(Young-Sub An),조동우(Dong Woo Joh),김혜성(Hye-Sung Kim),이승복(Seung-Bok Lee),임탁형(Tak-Hyoung Lim),박석주(Seok Joo Par 한국세라믹학회 2023 세라미스트 Vol.26 No.1
In the field of food and agriculture, fuel cell-based energy supply technology is gaining much attention for sustainable food systems with carbon neutrality by 2050. Previous studies have focused on the electricity balance using polymer electrolyte fuel cells (PEMFCs) without considering the temperature quality to maintain the environmental conditions required in smart farms. However, this study proposes a system that can provide all four energy sources (electricity, cooling, heating, and CO₂) required by smart farms by using solid oxide fuel cells (SOFC), which can utilize high-quality heat. To confirm the feasibility of the proposed idea, we demonstrate the world's first 10 kW-class SOFC-based integrated system for a smart farm in Jinju, South Korea. The system's core components consist of a SOFC system, a hot thermal storage system, a cold thermal storage system, and a CO₂ supply system. In this study, the applicability of the proposed system is verified by the experimental results of the effective production of cold and hot heat required by smart farms. In addition, the technical problems encountered during the demonstration are presented. In doing so, we suggest the direction of more economical and sustainable SOFC technology development for smart farm applications.
수중 환경에서 고분자 전해질 연료전지(PEMFC) 공급용 수소 생산을 위한 가압 디젤 개질시스템에 관한 연구
이광호,한광우,배중면,Lee, Kwangho,Han, Gwangwoo,Bae, Joongmyeon 한국군사과학기술학회 2017 한국군사과학기술학회지 Vol.20 No.4
Fuel cells have been spotlighted in the world for being highly efficient and environmentally friendly. A hydrogen which is the fuel of fuel cell can be obtained from a number of sources. Hydrogen source for operating the polymer electrolyte membrane fuel cell(PEMFC) in the current underwater environment, such as a submarine and unmanned underwater vehicles are currently from the metal hydride cylinder. However, metal hydride has many limitations for using hydrogen carrier, such as large volume, long charging time, limited storage capacity. To solve these problems, we suggest diesel reformer for hydrogen supply source. Diesel fuel has many advantages, such as high hydrogen storage density, easy to transport and also well-infra structure. However, conventional diesel reforming system for PEMFC requires a large volume and complex CO removal system for lowering the CO level to less than 10 ppm. In addition, because the preferential oxidation(PROX) reaction is the strong exothermic reaction, cooling load is required. By changing this PROX reactor to hydrogen separation membrane, the problem from PROX reactor can be solved. This is because hydrogen separation membranes are small and permeable to pure hydrogen. In this study, we conducted the pressurized diesel reforming and water-gas shift reaction experiment for the hydrogen separation membrane application. Then, the hydrogen permeation experiments were performed using a Pd alloy membrane for the reformate gas.