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잔류 불산에 의한 모델 지질토양시료의 광물 용해 및 비소 용출 특성
전필용,문희선,신도연,현성필,Jeon, Pilyong,Moon, Hee Sun,Shin, Doyun,Hyun, Sung Pil 한국지하수토양환경학회 2018 지하수토양환경 Vol.23 No.2
This study explored secondary effects of the residual hydrofluoric acid (HF) after a hypothetical acid spill accident by investigating the long-term dissolution of minerals and leaching of pre-existing arsenic (As) from two soil samples (i.e., KBS and KBM) through batch and column experiments. An increase in the HF concentration in both soil samples resulted in a dramatic increase in the release of major cations, especially Si. However, the amounts of mineral dissolved were dependent on the soil type and mineral characteristics. Compared to the KBM soil, relatively more Ca, Mg and Si were dissolved from the KBS soil. The column experiment showed that the long-term dissolution rates of the minerals are closely associated with the acid buffering capacity of the two soils. The KBM soil had relatively higher effluent pH values compared to the KBS soil. Also, more As was leached from the KBM soil, with a more amorphous hydrous oxide-bound As fraction. These results suggest that the potential of heavy metal leaching by the residual acid after an acid spill will be influenced by heavy metal speciation and mineral structure in the affected soil.
Controlled release of iron for activation of persulfate to oxidize orange G using iron anode
전필용,박상민,백기태 한국화학공학회 2017 Korean Journal of Chemical Engineering Vol.34 No.5
Persulfate (PS) can be activated by transition metal to generate a sulfate radical and oxidize persistent organic pollutants. However, activation with excessive Fe(II) causes unnecessary self-degradation of PS. In this study, Fe(II) was slowly and continuously injected electrochemically using an iron anode to minimize the self-degradation of PS. Additionally, reaction rate was controlled by adjusting the current intensity applied to the system. Total organic carbon (TOC) was analyzed as an indicator of complete mineralization because the model pollutant, orange G (OG), produced secondary pollutants after disruption of the azo bonds. The removal rate of TOC was 1/10-th of that for OG. In addition, the effect of molar ratio of OG and PS was also studied to confirm the complete mineralization of OG.
이명은,전필용,김종국,백기태 한국화학공학회 2018 Korean Journal of Chemical Engineering Vol.35 No.7
Biological wastewater treatment produces biowaste (sludge), which contains a high portion of organic matter. The organic matter comes from microorganisms, and the biowaste can be converted into biochar, a carbon-rich, fine-grained, and porous substance. Granular sludge from upflow anaerobic sludge blanket contains more organic matter (80 wt% of dry matter) and carbon content (>50% of organic matter). In this study, iron impregnated biochar was prepared to remove arsenic (As) and phosphate, oxyanionic pollutants, from the aqueous phase. The iron impregnation of biochar was executed in a one-step by pyrolyzing the biowaste in the presence of Fe instead of conventional two-step, i.e., biochar production after then modification. The granular sludge biochar and activated sludge biochar did not adsorb at all As and phosphate. The adsorption capacity of granular sludge biochar was enhanced via iron impregnation, and the iron-impregnated granular sludge biochar removed 10.37mg PO4 3/g, 11.5mg As(V)/g, and 6.1mg As(III)/g, respectively. Therefore, the one-step process enhanced the adsorption capacity and reduced processing time for the adsorbent synthesis.
Acid Sludge로 오염된 토양의 열탈착 공법 적용
박상민 ( Sang-min Park ),전필용 ( Pil-yong Jeon ),신수연 ( Su-yeon Shin ),박응렬 ( Eung-ryeol Park ),고성환 ( Sung-hwan Go ),정홍배 ( Hong-bae Jung ),백기태 ( Ki-tae Baek ) 한국환경기술학회 2016 한국환경기술학회지 Vol.17 No.1
본 연구는 Acid sludge 폐기물 매립에 의한 탄화수소로 오염된 인도네시아 정유플랜트 부지 토양을 대상으로 초기특성분석 및 열중량 분석(TGA-DSC)을 통해 열탈착 공법의 적용가능성을 확인하였다. 해당부지의 오염물질 성분은 GC/FID 분석을 통해 고체성분의 paraffin (C<sub>18</sub>H<sub>38</sub>~C<sub>37</sub>H<sub>76</sub>) wax계열로 확인되었다. 열중량 분석을 통해 질량변화가 가장 많은 구간은 364~461℃사이로 확인되었으며 이것은 이 온도 구간에서 대부분의 유기물이 제거되는 것을 나타낸다. 또한 약 400℃에서 가장 높은 DSC그래프가 나타났기 때문에 대부분의 유류오염물질들은 400℃에서 제거될 것으로 예상되었다. 이 결과를 기초로 열탈착 실험을 한 결과, 오염토양의 최적 열탈착 온도 조건은 약 350℃로 나타났으며 이 온도에서 TPH 농도는 인도네시아 환경기준 이하로 제거되었다. This study investigated the potential of thermal desorption of the soil contaminated with hydrocarbon in refinery site, Indonesia, which was contaminated by landfilling acid sludge. In this study, the characteristics of contaminated soil was confirmed and thermal gravimetric analysis (TGA) and differential scanning calorimeter (DSC) analysis were carried out. Contaminant was confirmed as paraffin (C<sub>18</sub>H<sub>38</sub>~C<sub>37</sub>H<sub>76</sub>) wax. In the results of TGA-DSC, the most of the organic matter was removed at 364~461℃ and the most contaminants was desorbed at 400℃. Based on these results, the optimum condition of thermal desorption was expected to 350℃ and hydrocarbons in the soil was removed under Indonesia standard in the temperature range