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이학기,임용진,민경은,최흥진,Hak-Ki Lee,Yong Jin Lim,Kyung Eun Min,HeungJin Choi 대한화학회 1984 대한화학회지 Vol.28 No.6
We obtained fast dyed polypropylene fiber, which has no functional group to be dyed, by producing a carbene on the dye molecule by the pyrolysis of lithium salt of dye molecule-tosylhydrazone, then the carbene simultaneously inserted into a C-H bond of polypropylene. To investigate the possibility of actual use in the industry, a variety of reactive azo dyes were prepared from aldehyde, acetophenone and benzophenone derivatives by changing reactive site of precursors which greatly affected properties of dyes. Reactive dyes of the benzophenone derivatives were excellent in the reaction with polypropylene, especially, a dye prepared from chloroaminobenzophenone with N,N-dimethyl aniline was found most excellent. 難染性纖維인 폴리프로필렌用 反應性染料를 開發하기 위하여 反應部位로서 카르벤을 染料에 生成케하여 폴리프로필렌의 C-H結合에 揷入反應을 시켜 堅固한 染着物을 얻을 수 있었다. 反應性카르벤染料의 前驅體로서 알데히드係, 메틸케톤係 및 페닐케톤係 反應性染料를 合成하고 카보닐基에 토실히드라진 및 부틸리튬을 各各 作用하여 各種染料의 토실히드라존리튬鹽을 만들어 폴리프로필렌상에서 加熱分解시킴으로써 染料分子에 生成된 카르벤이 폴리프로필렌에 共有結合을 하여 染着하였다. 여기에서 合成한 各種 카르벤染料들은 카르벤이 生成되는 隣接位에 있는 置換基의 種類와 位置에 따라 反應性에 差異點을 나타내었다. 특히 페닐케톤係 反應性染料가 反應性이 優秀하였으며 이들 페닐케톤係 反應性染料의 前驅體中에서도 클로로基를 가지는 클로로아미노벤조페논으로부터 合成한 染料가 他에 비해 反應性이 良好하였다.
1,4-Bisdiazo-2-butene의 合成과 그 化學的 性質의 硏究
이학기,Hak-Ki Lee 대한화학회 1969 대한화학회지 Vol.13 No.4
Synthesis and chemical properties of 1,4-bisdiazo-2-butene have been studied. 1,4-Bisdiazo-2-butene which was very unstable produced in protic solvents 1,3-butadiene and one unidentified substance instead of ring compounds. The reaction in aprotic solvents remains for further investigations.
小員環 化合物에 關한 硏究 (II) 2-Butenedial Ditosylhydrazone 熱分解에 있어서의 Tetrahedrane 生成에 關하여
이학기,Hak-Ki Lee 대한화학회 1969 대한화학회지 Vol.13 No.4
trans-1, 4-Dideutero-2-butenedial ditosylhydrazone has been synthesized to investigate the path of the acetylene formation in the pyrolysis of the dry lithium salt. Mass spectra showed that three isotope isomers of acetylene which might come from the strained ring compound, tricyclo[1, 1, 0, ?$0^{2, 4}$] butane, were formed.
이학기,임용진,최정도,Lee Hak-ki,Lim Yong Jin,Choi Jung Do 대한화학회 1974 대한화학회지 Vol.18 No.3
저자들은 tetrahedrane생성의 전구체인 t-butenedial bistosylhydrazone의 입체적인 구조를 연구할 목적으로 이의 유사한 구조인 ${\alpha},{\beta}$위치에 이중결합을 가지고 있는 몇 가지 phenylhydrazone을 합성하고 이들의 형태 및 배위를 nmr spectra의 해석으로부터 구명했다. 벤젠용매와 aliphatic solvent(CC14, DMSO)에서의 chemical shift의 차이로 부터 이들 물질이 syn-configuration을 가지고 있음을 알았으며 spin-spin coupling constant 로부터 이들 물질의 형태를 고찰하였다. Conformations and cofigurations were studied for some ${\alpha},{\beta}$-unsaturated phenylhydrazones which have similar structures to the stucture of butenedial bistosylhydrazone, a precursor of tetrahedrane, by the analysis of their nmr spectra. The chemical shift difference between two solvents, benzene and aliphatic solvents, was applied for the assigning syn and anti structures of phenylhydrazone isomers as a convenient method. In this work, it was found that the phenylhydrazones have syn configurations and also found that the dihedral angles of $CH_a-CH_b$ are around $150^{\circ}$ at room temperature from the the interpretation of the vicinal spin-spin coupling constants. These results were discussed in concerning with their conformations.
小員環 化合物에 關한 硏究 (I) 2-Butenedial Ditosylhydrazone의 熱分解에 關하여
이학기,Hak-Ki Lee 대한화학회 1969 대한화학회지 Vol.13 No.4
The synthesis and pyrolysis of trans-2-butenedial ditosylhydrazone with sodium methoxide in aprotic solvents have been studied to investigate the products of pyrolysis. The pyrolysis of dry lithium salt of tosylhydrazone also has been made, one of its products was acetylene which might come from a certain strained ring compound.
trans-2-Butenedial Bishydrazone의 NMR Spectrum에 對한 計算
이용태,이학기,Lee Yong Tae,Lee Hak-ki 대한화학회 1977 대한화학회지 Vol.21 No.4
새로이 合成한 화합물인 trans-2-butenedial bishydrazone의 AA'BB' 型 NMR 스펙트럼에 나타난 피이크는 모두 2개의 line이 重疊되어 있어서 보통의 방법으로는 internal check이 불가능하다. 5가지 파라미터 ${\delta}$, K, M, N, L을 漸次的으로 변화시켜 二重線의 中間點이 실제 line의 위치에 接近하게끔 함으로써 정확한 line의 位置를 알아내었으며 그 결과로부터 chemical shift와 coupling constant의 값을 구하였다. The NMR spectrum of newly synthesized compound, trans-2-butenedial bishydrazone is analyzed. It is found that each peak in the AA'BB' spectrum of the compound is consisted of two lines and internal check cannot be accomplished by the usual analytical procedure. Correct line positions are obtained by varying gradually all the parameters, ${\delta}$, K, M, N, L so that the mid points of the doublets may approach observed line positions and the chemical shifts and the coupling constants of the compound are obtained from the result.