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MeOH-MeCN 혼합용매 속에서의 2-naphthalenesulfonyl chloride의 가용매 분해반응 메카니즘에 관한 연구
김형태,신숙호 釜山大學校 師範大學 1993 교사교육연구 Vol.26 No.-
Kinetic study has been carried out conductimetrically on the methanolysis of 2-Naphthalenesulfonyl Chloride excluded from steric hindrance of peri-hydrogen in methanol-acetonitrile solvent mixtures at different temperatures. The usual behavior of maximal rate against methanol content was not found at any temperatures performed. The result that participation number of methanol is two at transition state bears out the push-pull concerted one-step mechanism.