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      • KCI등재

        TiN 및 WC코팅된 치과용 어버트먼트 나사의 안정성

        손미경(M.K. Son),이충환(C.H. Lee),정재헌(C.H. Chung),정용훈(Y.H. Jeong),최한철(H.C. Choe) 한국표면공학회 2008 한국표면공학회지 Vol.41 No.6

        Dental implant system is composed of abutment, abutment screw and implant fixture connected with screw. The problems of loosening/tightening and stability of abutment screw depend on surface characteristics, like a surface roughness, coating materials and friction resistance and so on. For this reason, surface treatment of abutment screw has been remained research problem in prosthodontics. The purpose of this study was to investigate the stability of TiN and WC coated dental abutment screw, abutment screw was used, respectively, for experiment. For improving the surface characteristics, TiN and WC film coating was carried out on the abutment screw using EB-PVD and sputtering, respectively. In order to observe the coating surface of abutment screw, surfaces of specimens were characterized, using field emission scanning electron microscope(FE-SEM) and energy dispersive x-ray spectroscopy(EDS). The stability of TiN and WC coated abutment screw was evaluated by potentiodynamic, and cyclic potentiodynamic polarization method in 0.9% NaCl solution at 36.5±1℃. The corrosion potential of TiN coated specimen was higher than those of WC coated and non-coated abutment screw. Whereas, corrosion current density of TiN coated screws was lower than those of WC coated and non-coated abutment screw. The stability of screw decreased as following order; TiN coating, WC coating and non-coated screw. The pitting potentials of TiN and WC coated specimens were higher than that of non-coated abutment screw, but repassivation potential of WC coated specimen was lower than those of TiN coated and non-coated abutment screws due to breakdown of coated film. The degree of local ion dissolution on the surface increased in the order of TiN coated, non-coated and WC coated screws.

      • KCI등재

        다양한 유사체액과 인공타액에서 치과용 임플란트의 전기화학적 특성

        김태한(T. H. Kim),박근형(G. H. Park),손미경(M. K. Son),김원기(W. G. Kim),장승현(S. H. Jang),최한철(H. C. Choe) 한국표면공학회 2008 한국표면공학회지 Vol.41 No.5

        Titanium and its alloy have been widely used in dental implant and orthopedic prostheses. Electrochemical characteristics of dental implant in the various simulated body fluids have been researched by using electrochemical methods. Ti-6Al-4V alloy implant was used for corrosion test in 0.9% NaCl, artificial saliva and simulated body fluids. The surface morphology was observed using scanning electron microscopy (SEM) and energy dispersive x-ray spectroscopy (EDX). The electrochemical stability was investigated using potentiosat (EG&G Co, 263A). The corrosion surface was observed using scanning electron microscopy (SEM). From the results of potentiodynamic test in various solution, the current density of implant tested in SBF and AS solution was lower than that of implant tested in 0.9% NaCl solution. From the results of passive film stability test, the variation of current density at constant 250 mV showed the consistent with time in the case of implant tested in SBF and AS solution, whereas, the current density at constant 250mV in the case of implant tested in 0.9% NaCl solution showed higher compared to SBF and AS solution as time increased. From the results of cyclic potentiodynamic test, the pitting potential and |Epit ? Ecorr| of implant tested in SBF and AS solution were higher than those of implant tested in 0.9% NaCl solution.

      • KCI등재

        Ti-30Ta-(3~15)Nb 합금에 HA/Ti 복합 코팅한 표면의 교류임피던스 특성

        정용훈(Y. H. Jeong),이호종(H. J. Lee),문영필(Y. P. Moon),박근형(G. H. Park),장승현(S. H. Jang),손미경(M. K. Son),최한철(H. C. Choe) 한국표면공학회 2008 한국표면공학회지 Vol.41 No.5

        A.C. impedance properties of HA/Ti compound layer coated Ti-30Ta-(3~15)Nb alloys have been studied by electrochemical method. Ti-30Ta binary alloys contained 3, 7, 10 and 15 wt% Nb were manufactured by the vacuum furnace system. And then specimen was homogenized at 1000℃ for 24 hrs. The sample was cut and polished for corrosion test and coating. It was coated with HA/Ti compound layer by magnetron sputter. The non-coated and coated morphology of Ti alloy were analyzed by X-ray diffractometer (XRD), energy X-ray dispersive spectroscopy (EDX) and filed emission scanning electron microscope (FE-SEM). The corrosion behaviors were investigated using A.C. impedance test (PARSTAT 2273, USA) in 0.9% NaCl solution at 36.5±1℃. Ti-30Ta-(3~15 wt%)Nb alloys showed the α+β phase, and β phase peak was predominantly appeared in the case of increasingly Nb contents. The microstructures of Ti alloy were transformed from needle-like structure to equiaxed structure as Nb content increased. From the analysis of coating surface, HA/Ti composite surface uniformed coating layer with 750 ㎚ thickness. The growth directions of film were (211), (112), (300) and (202) for HA/Ti composite coating on the surface after heat treatment at 550oC, whereas, the growth direction of film was (110) for Ti coating. The polarization resistance (Rp) of HA/Ti composite coated Ti-alloys were higher than those of the Ti and HA coated samples in 0.9% NaCl solution at 36.5±1℃. Especially, corrosion resistance of Ti-Ta-Nb system increased as Nb content increased.

      • KCI등재

        ZrN 및 TiN 코팅된 치과교정 용 미니나사의 표면특성과 전기화학적 거동

        김신영(S. Y. Kim),문영필(Y. P. Moon),박근형(G. H. Park),조호형(H. H. Jo),김원기(W. G. Kim),손미경(M. K. Son),최한철(H. C. Choe) 한국표면공학회 2008 한국표면공학회지 Vol.41 No.5

        The dental orthodontic mini-screw requires good mechanical properties and high corrosion resistance for implantation in the bone. The purpose of this study was to investigate the electrochemical characteristics of TiN and ZrN coated orthodontic mini-screws, mini-screws were used for experiment. Ion plating was carried out for mini-screw using Ti and Zr coating materials with nitrogen gas. Ion plated surface of each specimen w as o bserved with f ield emission scanning e lectron microscopy ( FE-SEM), e nergy dispersive x -ray spectroscopy (EDX), and electrochemical tester. The surface of TiN and ZrN coated mini-screw were more smooth than that of other kinds of non-coated mini-screw due to dercrease of machined defects. The corrosion current density of the TiN and ZrN coated mini-screw decreased compared to non-coated sample. The corrosion potential of TiN and ZrN coated mini-screw were higher than that of non-coated mini-screw in 0.9% NaCl solution. The pitting corrosion resistance increased in the order of ZrN coated, TiN coated and non-coated wire. Pitting potential of ZrN coated mini-screw was the highest in the other specimens.

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