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가시광을 이용한 ZnS/ZnO 상에서의 광촉매 반응에 의한 물로부터의 수소생성
서승광,윤필상,이한수,이호인 한국공업화학회 2003 응용화학 Vol.7 No.2
The pure ZnS can not absorb visible light because of its large band gap of 3.6eV. The ZnO/ZnS was obtained from partial oxidation of ZnS, and its band gap was 2.5eV where visible light can be absorbed. From XRD analysis, it was confirmed that only ZnO was formed during oxidation process but not ZnSO₄. In case of ZnO/ZnS, the quantum efficiency for the hydrogen evolution from water was 0.87% under visible light irradiation. In order to improve the interaction between ZnO and ZnS, ZnS/ZnO was prepared by precipitating ZnS on ZnO. After calcination of ZnS/ZnO, the band gap became narrow. The pure ZnO and the physically mixed ZnS-ZnO could not absorb visible light, but the ZnS-doped ZnO (ZnS/ZnO) could do. The band gap of pure ZnO was 3.2 eV and that of ZnS/ZnO was 2.5ev. The best activity was obtained when clcination temperature and time were 500 ℃ and 1 h, respectively. The quantum efficiency of ZnS/ZnO for the reaction was 3.29%.