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백영석 ( Young Seog Beck ),손진식 ( Jin Sik Sohn ) 한국물환경학회 2005 한국물환경학회지 Vol.21 No.2
Chlorination of wastewater is recently practiced in Korea. While many researchers have studied the kinetics of aqueous chlorine(HOCl) with nitrogeneous compounds and other organic/inorganic contaminants in drinking water, the researches of wastewater chlorination are relatively few. The purpose of this study was to investigate the chlorine decay kinetics and parameters on wastewater chlorination. Chlorine decay rate increased with increasing initial chlorine concentration. The parameters affecting chlorine decay rate were different in each wastewater treatment plant. One of the most important parameters affecting chlorine decay was initial chlorine concentration, and other parameters such as NH₃-N, total coliform, UV_(254) and Fe were also affected. The decay ratio of chlorine was decreased with increasing initial chlorine concentration, and the disinfection efficiency showed good correlation with the decay ratio.
건강위해성 평가에 의한 정수용 수처리제의 불순물 관리 기준 설정 방법에 관한 연구
정용 ( Yong Chung ),백영석 ( Young Seog Beck ),권동식 ( Dong Sik Kwon ),이기공 ( Ki Gong Lee ),강형석 ( Hyeong Seok Kang ) 한국물환경학회 2004 한국물환경학회지 Vol.20 No.5
The principle and methodology of risk assessment was applied to establish the quality standard of potential impurities of drinking water treatment chemicals. The impurities(arsenic, lead, cadmium, chromium, mercury, etc.) are regulated as the contained quantity of chemicals in Korea while they are regulated as the quality standard with the idea of 10% of the national safety drinking water standard in U.S.A(NSF) and Japan(JWWA). According to risk assessment of the current standard implemented in Korea, the excess cancer risk of arsenic and lead were determined in around 10^(-5) and the hazard quotient(HQ) of cadmium and chromium were below 10^(-2), respectively. And the standard concentration of the impurities are regulated as much as 2%~6% of the national drinking water quality standard. The values are more enforced rather than the standards in U.S.A(NSF) and Japan(JWWA) regulating the concentration of impurities the 10% of the national drinking water quality standard. We conclude that the impurities standard of drinking water treatment chemicals should be reconsidered comprehensively concerning the national safety drinking water quality standard and risk assessment.
백영석,송민형,정경훈,권동식,이기공 한국물환경학회 2004 한국물환경학회지 Vol.20 No.3
This study was performed to investigate the disinfection efficiency and the formation characteristics of disinfection by-products(DBPs) by chlorination in the sewage effluent. The effluent was sampled from the sewage treatment plants operated in the activated sludge process and the advanced sewage process. The type of DBPs investigated were Trihalomethanes(THMs), Dichloroacetonitrile(DCAN), Chloral hydrate(CH), Dichloroacetic acid(DCAA), Trichloroacetic acid(TCAA). Major findings are as follows. First, the optimum injection concentration for chlorination in sewage effluent were found to be in the range 0.5 ~ 1.0 ㎎ Cl₂/L. Also, It was found that the chlorine dosage in the effluent of activated sludge process was higher than in the effluent of advanced sewage process. Second, the maximum formation concentration of THMs were 12.7 μg/L. The THMs formation reaction was finished in a short time of several seconds and chloroform was mainly formed. Also, it was found that the concentration of ammonium nitrogen is higher, the concentration of THMs is lower. Third, it was found that DCAA and TCAA were mainly formed as DBPs by disinfection.