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NH₃-O₂-Ar 혼합기체의 점화 과정에서 H₂기체의 첨가 효과에 관한 연구
신권수,배균택 崇實大學校 2000 論文集 Vol.30 No.1
The addition effect of H₂on ignition of NH₃-O₂-Ar mixtures was examined in the temperature range of 1521-2193 K and the pressures in the range of 0.86-1.78 bar behind reflected shock waves. The ignition delay times were measured by monitoring pressure profiles and the OH emissions at 1.0 cm from the end wall. To complement the experiment, computer modeling study of the ignition of NH₃-O₂-Ar mixtures was carried out using various mechanisms reported previously.
면역 부전 환자에서 병발한 급성 황색 포도상 구균에 의한 세균성 식도염 1예
박환양,김춘관,박영배,박재완,김성훈,강정원,문경협,양수현,변종훈 대한감염학회 2001 감염 Vol.33 No.5
Bacterial esophagitis is an uncommon disease and has not been well characterized. Bacterial infection of the esophagus is usually presented as a superimposed infection upon a preexisting viral or fungal esophagitis and most patients are immunocompromised hosts. A 67-year-old man was admitted for retrosternal pain and hematemesis, who had a past history of long-standing diabetes mellitus and end stage renal disease, also had a history of steroid medication. Extensive esophageal ulcerations of the mucosa were visualized by endoscopy. Staphylococcus aureus grew in blood culture. After the 2 weeks of antibiotics treatment, he was successfully recovered without any sequelae. Due to its rarity, this case is herein reported with a review of the corresponding literature. (Korean J Infect Dis 33:360∼363, 2001)
Shin, Kuan Soo,Cho, Young Kwan,Kim, Kyung Lock,Kim, Kwan Korean Chemical Society 2014 Bulletin of the Korean Chemical Society Vol.35 No.3
In this work, we describe a very simple electroless deposition method to prepare moderate-SERS-active nanostructured Pd films deposited on the glass substrates. To the best of our knowledge, this is the first report on the one-pot electroless method to deposit Pd nanostructures on the glass substrates. This method only requires the incubation of negatively charged glass substrates in ethanol-water mixture solutions of $Pd(NO_3)_2$ and butylamine at elevated temperatures. Pd films are then formed exclusively and evenly on glass substrates. Due to the aggregated structures of Pd, the SERS spectra of benzenethiol and organic isonitrile could be clearly identified using the Pd-coated glass as a SERS substrate. This one-step fabrication method of Pd thin film on glass is cost-effective and suitable for the mass production.
Surface-Enhanced Raman Scattering of Benzenethiol Adsorbed on Silver-Exchanged Copper Powders
Shin, Kuan-Soo,Ryoo, Hyun-Woo,Lee, Yoon-Mi,Kim, Kwan Korean Chemical Society 2008 Bulletin of the Korean Chemical Society Vol.29 No.2
Micrometer-sized copper (mCu) powders are weakly surface-enhanced Raman scattering (SERS) active by the excitation at 632.8 nm, but nearly ineffective as a SERS substrate at 514.5 nm excitation. The SERS activity of mCu powders at both excitation wavelengths can be increased dramatically by a simple method of the galvanic exchange reaction with AgNO3 in aqueous medium. In this work, the SERS activity of the Ag-exchanged Cu powders (mCu@Ag) has been evaluated by taking a series of Raman spectra using benzenethiol (BT) as the probe molecule. It is clearly confirmed by field emission scanning electron microscopy and X-ray diffractometry that the SERS activity of mCu@Ag powders is, in fact, highly dependent on the extent of galvanic reaction.
Shock Tube and Modeling Study of the Monomethylamine Oxidation at High Temperature
Shin, Kuan-Soo,Yoo, Sang-Jo Korean Chemical Society 2004 Bulletin of the Korean Chemical Society Vol.25 No.2
The ignition of monomethylamine was studied in reflected shock waves over the temperature range of 1255- 1579 K and the pressure range of 1.04-1.51 bar. The ignition delay time was measured by the sudden increase of pressure profile and the radiation emitted by OH radicals. The relationship between the ignition delay time and the concentrations of monomethylamine and oxygen was determined in the form of mass-action expressions with an Arrhenius temperature dependence. In contrast to the behavior observed in hydrocarbons, monomethylamine acts to accelerate rather than inhibit its own ignition. And numerical modeling of the ignition of $CH_3NH_2$ has also been carried out to test the several kinetic mechanisms.