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Effect of Interfacial Segregation on Phase Decomposition of a Thin Film on a Patterned Substrate
Johnson, William C.,Wise, S.M.,Huh, J.Y.,Favergeon, J 대한금속재료학회 2003 METALS AND MATERIALS International Vol.9 No.1
Numerical simulations of phase decomposition in thin films on patterned substrates are presented for a binary alloy in order to study the influence of substrate composition on microstructural evolution. For systems with a substrate composition less than the film composition, a preferential segregation of A to the interface was observed and no phase decomposition occurred within the film. For patterned systems with a substrate composition exceeding the film composition, the B-rich phase was able to grow by a barrierless transformation for a range of film compositions outside the chemical spinodal. The number of precipitates which formed on the mesa, the dihedral angles at the three-phase trijunctions, and the resulting microstructure within the film were shown to be sensitive to the substrate composition.
김성환,허주열,Jae-Ho Jun,Joong-Hwan Jun,Jerome Favergeon 한국물리학회 2010 Current Applied Physics Vol.10 No.2
Thin elemental coatings of Y, Co, and Y/Co on a commercial ferritic stainless steel (AISI444) were investigated for their effects on the growth kinetics and area specific resistance (ASR) of the scale formed at 800 ℃. After oxidation for 1000 h, the ASR value of the Y-coated AISI444 was less than that of the corresponding uncoated sample by the factor of two, because of a significant retardation of scale growth. The Co coating also resulted in a decrease of the ASR value even though it significantly accelerated the scale growth. The effects of the Y and Co coatings on scale growth were associated with the growth kinetics of the chromia sublayer in the scale. The Y coating was most effective for solid oxide fuel cell (SOFC) interconnect applications because of the relatively low and stable ASR value with the lapse of oxidation time.