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Xiaopeng Huang,Feng Liang,Yuanchao Du,Keyu Zhang,Yaochun Yao,Yongnian Dai 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2016 NANO Vol.11 No.11
A systematic approach was used to develop the empirical model for optimizing the preparation process parameters for the synthesis of LiFe1-x-yMgxTiyPO4/C composite cathode material. For optimizing the production parameters, response surface methodology (RSM) was applied to develop a linear regression model and maximize the discharge capacity. Analysis of the variance (ANOVA) showed that the three variables (Mg-dopant, Ti-dopant and sintering temperature) and the interactions among them were significant factors. Response surfaces formed by RSM illustrated that the doping of Mg and Ti on Fe site had obviously synergistic effect on the discharge capacity. In the process optimization, the parameters were 2.9% of Mg-dopant, 3.0% of Ti-dopant and sintering temperature of 678.5℃, corresponding to a discharge capacity of 136.7 mAh/g predicted by the model. This predicted value was in good agreement with the actual value (136.4 mAh/g) by confirmatory experiment. The optimized LiFe0.941Mg0.029Ti0.030PO4/C composite exhibits a good rate performance and cycling stability due to the enhancement of electronic conductivity and lithium diffusion coefficient (3.1 X 10-12 cm2 /s) by the co-doping of Mg and Ti ions.
Zhongyao Zhang,Xiaopeng Chen,Jiezhen Liang,Xiaojie Wei,Kaixi Deng,Jiezhong Zou,Linlin Wang 한국공업화학회 2022 Journal of Industrial and Engineering Chemistry Vol.111 No.-
The petrol-based random copolymer, e.g., aromatic-hydrocarbon resin, is widely used in industrial production,but the research about its gas–liquid two flow is far from being solved. Herein, the formation,motion, and deformation of a single bubble in six different concentrations of random copolymer solutionswere systemically investigated using high-speed photography (1000 fps), combined with digital imageprocessing technology. The departure time of the bubble first decreases and then increases, and maximumof aspect ratio and specific surface area reduce as the proportion of solute increases. The bubbledeparture time decreases and bubble size increases with viscous force increases in the case of same surfacetension. Based on force balance analysis, added mass force is one of the prime reasons to affect bubbleoscillation during the acceleration phase after bubble detachment, whereas the effect of added massforce decreases as solute increases or as the bubble reaches stability zone. Also, velocity, drag coefficientand aspect ratio of bubble were discussed in detail by dimensionless analysis. Furthermore, three newshape numerical models (based on We, Ta, and WeEo, respectively) were proposed, which allowed for satisfactorypredictions, and new correlations represent well the experimental data in a wider range of Monumbers from the mentioned literature (11.6 logMo 0.63).
Dan Xiao,Xiaoyan Peng,Xiaopeng Liang,Ying Deng,Guofu Xu,Zhimin Yin 대한금속·재료학회 2017 METALS AND MATERIALS International Vol.23 No.3
Hot compression tests of as-homogenized Al-Zn-Mg-Cu alloy were performed at the deformation temperaturerange of 350-450 °C and the strain rate range of 0.001-1 s-1. The Arrhenius-type constitutive equation and theAvrami-type model were established to predict the flow behaviors of the alloy respectively. The processing map atthe true strain of 0.92 was developed to evaluate the workability of the alloy and the related microstructures wereinvestigated. The results show that the Avrami-type model has a higher accuracy to predict flow stress than theArrhenius-type constitutive equation. The stable deformation occurs under high temperature or low strain ratemainly owing to the dynamic recrystallization. Flow instability is prone to occur under the condition of low temperatureand high strain rate due to the initiation and the propagation of micro-cracks. According to the processingmap and corresponding microstructure characteristics, the optimum processing parameters are in the temperaturerange of 380-405 °C and the strain rate range of 0.006-0.035 s-1.
Review of Vasectomy Complications and Safety Concerns
Yang Fang,Li Junjun,Dong Liang,Tan Kun,Huang Xiaopeng,Zhang Peihai,Liu Xiaozhang,Chang Degui,Yu Xujun 대한남성과학회 2021 The World Journal of Men's Health Vol.39 No.3
Vasectomy is a simple, safe, effective, and economical method used worldwide for long-term male contraception. As a sur-gical operation, it has short-term and long-term complications such as hematoma formation, infection, sterilization failure, sperm granulomas, short-term postoperative pain (nodal pain, scrotal pain, and ejaculation pain), and chronic pain syn-drome. Whether it increases the risk of autoimmune disease, cardiovascular disease, testicular cancer, or prostate cancer is still controversial. Changes in plasma concentrations of luteinizing hormone, follicle-stimulating hormone, and testosterone after vasectomy have also been studied, as well as the relation between vasectomy and sexual function. Sperm quality de-creases very slowly after vasectomy, and vasovasostomy and intracytoplasmic sperm injection could help a couple achieve a pregnancy if they change their minds at any point. We include a follow-up strategy and suggestions for follow-up care at the end of this review.
Dongdong Wang,Yang Lu,Zhuo Sun,Wei Liang,Dongshu Sun,Changli Qi,ChengZhuo Sheng,Xiaopeng Yu 한국화학공학회 2020 Korean Journal of Chemical Engineering Vol.37 No.2
An aqueous two-phase system (ATPS) containing an ionic liquid (1-(2-methoxyethyl)-3-methylimidazolium bromide) and three organic salts (K3C6H5O7, (NH4)3C6H5O7, and K2C4H4O6) at different temperatures was designed. Binodal data were correlated using two empirical equations, and tie-line data were fit with the utilization of Bancroft and Othmer-Tobias equations. In the systems investigated, three conclusions were drawn from the study of the phase-forming ability of salt through effective excluded volume, Gibbs free energy of ions, and the phase diagram. First, if the same cations of salt were present, the ability of salt to form phases increased with increasing valence of the anion. Second, the larger the effective excluded volume, the stronger the aforementioned ability of salt in forming phases. Third, salt had more ability to form phases if cations (or anions) contained in the salt possessed higher negative Gibbs free energy when the cation (anion) of the salt was the same. The effect of temperature on ATPSs was also investigated. It was found that it was easier to form ATPSs at lower temperature, and the tie-line slope showed growing absolute values as the temperature was decreased.