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Afrasyab Khan,Mohd Sobri Takriff,Masli Irwan Rosli,Nur Tantiyani Ali Othman,Khairuddin Sanaullah,Andrew Ragai Henry Rigit,Ajmal Shah,Atta Ullah 한국화학공학회 2020 Korean Journal of Chemical Engineering Vol.37 No.1
Handling and utilization of steam flow efficiently to obtain various tangible industrial outcomes relies mainly upon how to optimize various flow parameters like boundary layer thickness, skewness, shear stress, and turbulent dissipation for minimum losses such as pressure and heat. Swirling steam flow, driven by a propeller through a circular duct along horizontal and inclined surfaces presents an interesting flow regime that includes the boundary layer flows close to the wall of the pipe and weak and uniform flow that prevails across the inner region of the pipe. Such flow was investigated here with a specially designed experimental facility. Convective Instabilities were observed that propagate along the axial direction in a nonlinear fashion. It was observed that the operating conditions could be optimized for measuring the shear stresses based on the intersection of the profiles under the effect of variations in the inlet pressure of steam and the rotational speed of the propeller. We found that the flow transformed from positive to negative skewness when the rotational speed of the propeller was raised from 4-14 thousand per minute at 10 bars of constant inlet steam pressure. More area came under the effect of reduced skin friction when the rotational speed of the propeller was raised. More turbulent energy was found to be dissipated when the rotational speed of the propeller was raised. It was found that yet the dissipation of the turbulent energy takes place under the joint effect of inlet pressure of steam and the rotational speed of the propeller, but the exact effect of any one of these two operating parameters still needs to be determined and requires further investigation.
Inhibition of aluminum corrosion by phthalazinone and synergistic effect of halide ion in 1.0 M HCl
Ahmed Y. Musa,Abdul Amir H. Kadhum,Abu Bakar Mohamad,Mohd Sobri Takriff,Eng Pei Chee 한국물리학회 2012 Current Applied Physics Vol.12 No.1
The inhibitive effects of 1-(2H)-phthalazinone (PTO) for aluminum alloy (2024) corrosion in 1.0 M HCl solution and the synergistic effect of KI on the corrosion inhibition efficiency were assessed using electrochemical measurements. Results showed that the inhibition efficiency increased with an increase in concentration of the PTO and synergistically increased with addition of KI. Adsorption characteristic of PTO molecules in absence and presence of KI was approximated by Freundlich and Langmuir adsorption isotherm models, respectively. The synergistic effect is found to decrease with increase in the concentration of PTO and a competitive inhibition mechanism exists between KI and PTO cations.
Ahmed Y. Musa,Abu Bakar Mohamad,Abdul Amir H. Kadhum,Mohd Sobri Takriff,Waleed Ahmoda 한국공업화학회 2012 Journal of Industrial and Engineering Chemistry Vol.18 No.1
Quantum chemical calculations were performed on ten thio compounds using semi-empirical method PM3 within program package of Material Studio 5.5. The effect of molecular structure on the corrosion inhibition efficiency was investigated using the quantum chemical calculations. The electronic properties such as highest occupied molecular orbital (HOMO), lowest unoccupied molecular orbital (LUMO) energy levels, (LUMO–HOMO) energy gap, dipole moment (l) and fraction of electron transfer (DN) were calculated and discussed. A relationship between the corrosion inhibition efficiency and several quantum parameters was established with coefficient correlation (R2) of 0.8894.
Muneer M. Ba-Abbad,Abdul Amir H. Kadhum,Abu Bakar Mohamad,Mohd S. Takriff,Kamaruzzaman Sopian 한국공업화학회 2013 Journal of Industrial and Engineering Chemistry Vol.19 No.1
The experimental conditions for the synthesis of ZnO nanoparticles to produce minimal size were optimized using the D-optimal design. The influence of process parameters involves molar ratio of the starting materials, pH and the calcination temperature on the particle size were evaluated using the polynomial regression. The optimum conditions revealed by the model for obtaining a minimum particle size of ZnO were predicted to have a molar ratio of 1.76, pH of 1.50 and calcination at 402.2 8C. The obtainable particle size upon applying the model is 22.9 nm in compare to experimental result of 18 2 nm was obtained.
Removal of Rhodamine Dye from Water Using Erbium Oxide Nanoparticles
Luaibi, Hasan M.,Al-Taweel, Saja S.,Gaaz, Tayser Sumer,Kadhum, Abdul Amir H.,Takriff, Mohd S.,Al-Amiery, Ahmed A. Materials Research Society of Korea 2019 한국재료학회지 Vol.29 No.12
Environmental pollution remains a considerable health risk source all over the world; however, hazards are usually higher in developing countries. Iraq has long been suffering from the problem of pollution and how to treat pollution. Photocatalytic degradation has turned out to be most productive process for dye degradation. In this investigation, Rhodamine B (RhB), dye has been selected for degradation under visible light illumination. To address this issue, we fabricate erbium trioxide nanoparticles (Er<sub>2</sub>O<sub>3</sub>/NPs). Erbium trioxide nanoparticles are prepared and utilized for photo-catalytic degradation. The characterization of Er<sub>2</sub>O<sub>3</sub>/NPs is described and confirmed by utilizing of XRD (X-ray diffraction) and SEM (Scanning Electron Microscopy). The average size of Er<sub>2</sub>O<sub>3</sub> nanoparticles is observed to be 16.00 nm. Er<sub>2</sub>O<sub>3</sub>/NPs is investigated for its ability of photo-catalytic degradation through certain selected parameters such as concentration and time. The methodological results show that the synthesized Er<sub>2</sub>O<sub>3</sub>/NPs is a good photo-catalytic for Rhodamine degradation.