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      • KCI등재

        Degree of Hydration and Compressive Strength of Conditioned Samples Made of Normal and Blended Cement System

        Nasir Shafiq 대한토목학회 2011 KSCE JOURNAL OF CIVIL ENGINEERING Vol.15 No.7

        In this paper; results of the degree of hydration of the pastes and the compressive strength of the 50 mm cubes prepared with the 100% cement and fly ash blended cement were determined. 24 hours after casting mortar cubes and the paste samples were cured for 28 days in the fog room. After 28 days curing, a set of three cubes and a paste sample was dried in the 100%, 75%, 65%, 40% and 12% ambient relative humidity at the constant temperature of 27oC. Drying conditions showed significant effects on the compressive strength and the degree of hydration. Highest compressive strength of 70 MPa was measured of mortar cubes dried in 100% RH;similarly, 97% degree of hydration was obtained for 100% cement samples dried in the 100% RH. For mortar cubes dried in 12%RH, the compressive strength was measured between 47 and 53 MPa. The similar paste samples showed the maximum degree of hydration as 81%. Statistically valid correlations were obtained between the degree of hydration and the compressive strength of normal and blended cement system.

      • KCI등재

        Carbon nanotubes loaded N,S-codoped TiO2: Heterojunction assembly for enhanced integrated adsorptive-photocatalytic performance

        Maira Shabir,Nasir Shezad,Iqrash Shafiq,Ibrahim M. Maafa,Parveen Akhter,Kshaf Azam,Ashfaq Ahmed,See Hoon Lee,Young-Kwon Park,Murid Hussain 한국공업화학회 2022 Journal of Industrial and Engineering Chemistry Vol.105 No.-

        A visible-light active N,S-codoped TiO2 incorporated with carbon nanotubes (CNTs) was synthesized by amulticomponent heterojunction scheme. The synthesized photocatalysts was examined by several analysistechniques. The conventional TiO2, N-doped TiO2, TiO2/CNT and N,S-codoped TiO2 were also synthesized,characterized, and integrated adsorptive-photocatalytic degradation rates were subsequentlycompared and assessed, for comparative purposes as reference photocatalysts. The parametric studywas also carried out to investigate the effect of various operational factors, such as solution pH, the photocatalystloading and initial concentration of dye solution, on the adsorptive-photocatalytic performance. The best activity performance was attained with the N,S-TiO2/CNTs nanocomposite due to thesynergistic effect of ternary components caused by the incorporation of dopants and CNTs in TiO2 lattice,providing a high number of adsorption sites and facilitating the effective separation of photogeneratedcharge carriers and minimal recombination rates. N,S-TiO2/CNTs exhibited around three times higherphotocatalytic performance than that of the binary composites, i.e., N-TiO2, TiO2/CNTs, N,S-TiO2, andabout four times higher than the conventional TiO2. Furthermore, the superior nanocomposites were alsoinvestigated for their recyclability for five consecutive cycles.

      • KCI등재

        FRP as Strengthening Material for Reinforced Concrete Beams with Openings - A Review

        Siew Choo Chin,Nasir Shafiq,Muhd Fadhil Nuruddin 대한토목학회 2015 KSCE JOURNAL OF CIVIL ENGINEERING Vol.19 No.1

        This paper presents the review of studies performed to investigate the behavior of Reinforced Concrete (RC) beams containingdifferent types of openings. For the last 4 decades, research works involved the investigation of the member strength anddevelopment of the design approach for simply supported, continuous and T-beams containing large rectangular openings subjectedto torsion, bending and shear forces. The proposed design method suggested the installation of diagonal steel reinforcement barsaround the opening for providing the required strength. In recent years, Fiber Reinforced Polymers (FRP) have been widely used asan external bonded reinforcement system for upgrading and retrofitting of concrete structures. FRP as externally bondedreinforcement mainly used to repair and retrofit the damaged reinforced concrete member. However, very limited studies showed theapplication of the FRP laminates as external reinforcement around openings. Therefore, further investigations regarding theapplication of FRP laminates to strengthen the large openings in reinforced concrete members are very vital.

      • KCI등재

        Montmorillonite-Supported BiVO4 nanocomposite: Synthesis, interface characteristics and enhanced photocatalytic activity for Dye-contaminated wastewater

        Parveen Akhter,Iqrash Shafiq,Faisal Ali,Faiza Hassan,Roeya Rehman,Nasir Shezad,Ashfaq Ahmed,Farrukh Jamil,Murid Hussain,Young-Kwon Park 한국공업화학회 2023 Journal of Industrial and Engineering Chemistry Vol.123 No.-

        Textile effluents may harm the human body as well as cause environmental pollution. For several decadesresearchers have been attempting to overcome this issue by introducing environmentally friendly technologiesthat degrade bulk dyes to mitigate hazards. Synthetic dyes are carcinogenic for humans as wellas for other living organisms. Various techniques have been developed for the removal of these toxiccompounds, advanced oxidation processes (AOPs) being the most used processes. In this study,Montmorillonite (MMT) supported BiVO4 nanocomposite was prepared by the sol–gel method to degradeBrilliant Red 80 dye using photocatalysis. The BiVO4/MMT composite was comprehensively characterizedby several characterization techniques including X-ray diffraction (XRD), Fourier-transform infraredspectroscopy (FTIR), Scanning electron microscopy (SEM), Raman, Photoluminescence spectroscopy(PL), and UV–Vis diffuse reflectance spectroscopy (UV–Vis-DRS). Interestingly, the composite materialshowed a narrow bandgap of 2.26 eV with strong light absorption in the visible range. A 1000-wattXenon Lamp was used for activity performance measurement. The photocatalytic Brilliant Red 80 degradationactivity was observed to be 99% degraded within 120 min of illumination compared to conventionalBiVO4 which showed around 80% degradation. Moreover, in this work, an acidic media wasfound to favor the degradation of Brilliant Red 80 dye.

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