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Controlling the Magnetic Properties of the Van der Waals Ferromagnet Fe₃GeTe₂
Hyejin Ryu,Se Young Park,Dong Seob Kim,Yu Liu,Jinwoong Hwang,Younghak Kim,Wondong Kim,Jae-Young Kim,Cedomir Petrovic,Choongyu Hwang,Sung-Kwan Mo,Hyung-jun Kim,Byoung-Chul Min,Hyun Cheol Koo,Joonyeon C 한국자기학회 2021 한국자기학회 학술연구발표회 논문개요집 Vol.31 No.1
Identifying material parameters that affect magnetic properties of ferromagnets is key to optimize materials better suited for spintronics applications. Here, we propose an effective hole doping method to modulate the magnetic anisotropy of a van der Waals ferromagnet, and explore the physical origin of this effect. Experimental measurements of the doping and thickness dependent magnetic properties of thin Fe<sub>3-x</sub>GeTe<sub>2</sub> show a significant suppression of the magnetic anisotropy with hole doping. From the measured and calculated doping dependent electronic structure, we find that the energy gain by the spin-orbit induced band splitting is reduced by the chemical potential shift associated with hole doping, which in turn reduce the magnetic anisotropy energy. The identified mechanism provides an understanding of the doping induced modulation of magnetic properties in Fe<sub>3</sub>GeTe<sub>2</sub> thin films.
AHN, Mi-Jeong,YOON, Kee-Dong,MIN, So-Young,LEE, Ji Suk,KIM, Jeong Ha,KIM, Tae Gyun,KIM, Seung Hee,KIM, Nam-Gil,HUH, Hoon,KIM, Jinwoong WHO COLLABORATING CENTRE FOR TRADITIONAL MEDICINE 2004 東西醫學硏究所 論文集 Vol.2004 No.-
The bioassay-directed isolation of a marine brown alga, Ecklonia cava, afforded four phlorotannin derivatives, eckol (1), 8,8'-bieckol (2), 8,4'''-dieckol (3), and phlorofucofuroeckol A (4). Among these compounds, 2 and 3 exhibited an inhibitory effect an human immunodeficiency virus type 1 (HIV-1) reverse transcriptase (RT) and protease. Specifically, they inhibited the RT more potently than the protease. The inhibitory activity of compound 2 (IC_(50), 0.51 μм) against HIV-1 RT was comparable to that of nevirapine (IC_(50), 0.28 μм), a reference compound. An enzyme kinetic assay showed that this compound inhibited the RNA-dependent DNA synthesis activity of HIV-1 RT noncompetitively against dUTP/dTTP with a K_(i) value of 0.78 μM. With respect to the homopolymeric template/primer, (rA)_(n)(dT)_(15), 8,8'-bieckol (2) displayed an uncompetitive type of inhibition (K_(i), 0.23 μм).
Kim, Jinwoong,Kim, Jeongwoo,Song, Young-Sun,Wu, Ruqian,Jhi, Seung-Hoon,Kioussis, Nicholas American Physical Society 2017 Physical review. B Vol.96 No.23
<P>The interfacial phase-change memory (iPCM) GeTe/Sb2Te3, a promising candidate for the next generation nonvolatile random-accessmemories, exhibits fascinating topological properties. Depending on the atomic-layerstacking sequence of the GeTe block, the iPCM can be either in the SET (Ge-Te-Ge-Te) or RESET (Te-Ge-Ge-Te) states, where the former exhibits ferroelectric polarization and electrical conductivity two orders of magnitude larger than that of the RESET state. Yet, its microscopic origin remains elusive. Here, we predict the emergence of a Weyl semimetal phase in the SET state induced by the ferroelectric polarization which breaks the crystal inversion symmetry. We show that the giant conductivity enhancement of the SET phase is due to the appearance of gapless Weyl nodes. The Ge-Te-or Sb-Te-terminated surfaces of Weyl semimetal iPCM exhibit surface states with completely distinctive topology, where the former consists solely of Fermi arcs while the latter consists of both closed Fermi surface and open Fermi arcs. The iPCM with van der Waals interfaces offers an ideal platform for exploiting the exotic Weyl properties as well as for future memory device applications.</P>
Kim, Min Kyung,Yang, Dong-Hyug,Jung, Mihye,Jung, Eun Ha,Eom, Han Young,Suh, Joon Hyuk,Min, Jung Won,Kim, Unyong,Min, Hyeyoung,Kim, Jinwoong,Han, Sang Beom Elsevier 2011 Journal of chromatography A Vol.1218 No.37
<P><B>Abstract</B></P><P>Methods using high performance liquid chromatography with diode array detection (HPLC-DAD) and tandem mass spectrometry (HPLC–MS/MS) were developed and validated for the simultaneous determination of 5 chromones and 6 coumarins: prim-<I>O</I>-glucosylcimifugin (1), cimifugin (2), nodakenin (3), 4′-<I>O</I>-β-<SMALL>D</SMALL>-glucosyl-5-<I>O</I>-methylvisamminol (4), sec-<I>O</I>-glucosylhamaudol (5), psoralen (6), bergapten (7), imperatorin (8), phellopterin (9), 3′-<I>O</I>-angeloylhamaudol (10) and anomalin (11), in Radix Saposhnikoviae. The separation conditions for HPLC-DAD were optimized using an Ascentis Express C18 (4.6mm×100mm, 2.7μm particle size) fused-core column. The mobile phase was composed of 10% aqueous acetonitrile (A) and 90% acetonitrile (B) and the elution was performed under a gradient mode at a flow rate of 1.0mL/min. The detection wavelength was set at 300nm. The HPLC-DAD method yielded a base line separation of the 11 components in 50% methanol extract of Radix Saposhnikoviae with no interfering peaks detected. The HPLC-DAD method was validated in terms of linearity, accuracy and precision (intra- and inter-day), limit of quantification (LOQ), recovery, and robustness. Specific determination of the 11 components was also accomplished by a triple quadrupole tandem mass spectrometer equipped with an electrospray ionization (ESI) source. This HPLC–MS/MS method was also validated by determining the linearity, limit of quantification, accuracy, and precision. Quantification of the 11 components in 51 commercial Radix Saposhnikoviae samples was successfully performed using the developed HPLC-DAD method. The identity, batch-to-batch consistency, and authenticity of Radix Saposhnikoviae were successfully monitored by the proposed HPLC-DAD and HPLC–MS/MS methods.</P>
Kim, Young-Mi,Chae, Hee-Sung,Lee, Eun Joo,Yang, Min Hye,Park, Jin Hee,Yoon, Kee Dong,Kim, Jinwoong,Ahn, Hee Chul,Choi, Young Hee,Chin, Young-Won Pharmaceutical Society of Japan 2014 Biological & pharmaceutical bulletin Vol.37 No.5
<P>Citrus species has been traditionally used in Korea for the treatment of coughing, sputum and dyspepsia. Of the known citrus flavonoids, 6-demethoxytangeretin was reported to exert anti-inflammatory activity. In order to determine the anti-allergic activity of 6-demethoxytangeretin, we examined whether or not 6-demethoxytangeretin was able to suppress activation of the human mast cell line, HMC-1, induced by phorbol 12-myristate 13-acetate (PMA) plus A23187. Interleukin-6 production and relevant gene expression in activated HMC-1 cells were determined by enzyme-linked immunosorbent assay (ELISA) and quantitative reverse transcription-polymerase chain reaction (RT-PCR) analysis. Also, the involvement of the anaplastic lymphoma kinase (ALK) and mitogen-activated protein kinases (MAPKs) in activated HMC-1 cells were studied. 6-Demethoxytangeretin suppresses interleukin-6 production, tumor necrosis factor-alpha gene expression, ALK and MAPKs in HMC-1 cells stimulated by PMA plus A23187. Therefore, it was evident that 6-demethoxytangeretin suppressed activation of HMC-1 cells by PMA plus A23187 by inhibiting the activity of ALK and MAPKs and subsequently suppressing gene expression, which suggest that 6-demethoxytangeretin may be involved in the regulation of mast cell-mediated inflammatory responses.</P>