http://chineseinput.net/에서 pinyin(병음)방식으로 중국어를 변환할 수 있습니다.
변환된 중국어를 복사하여 사용하시면 됩니다.
Comment on the Interpretation of Hund's Multiplicity Rule
Y.Ishigaki,M.Higuchi,H.Yasuhara 한국물리학회 2002 THE JOURNAL OF THE KOREAN PHYSICAL SOCIETY Vol.40 No.6
According to conguration interaction calculations of light atoms, ions , and molecules, the lower energy of the high-spin state arising from the same conguration is due to its greater electronnucleus attraction, in contrast with the traditional explanation of Hund's rule which assumes a greater electron repulsion in the lower spin states. On the contrary, the electron-electron repulsion is found to be greater in the high-spin state of every neutral species. Aiming at a systematic interpretation of Hund's rule, we here sketch a new method of performing accurate calculations for heavier atoms and molecules, which uses an orbital-dependent correlation energy functional based on density-functional theory.