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Qingyu Zhang,Xiaoling Duan,Siyi Tang,Cunwen Wang,Weiguo Wang,Weiliang Feng,Tielin Wang 대한환경공학회 2023 Environmental Engineering Research Vol.28 No.1
In this study, a series of acid-base bi-functional catalysts were prepared by mixing different amounts of basic amino acids (AAs) and phosphotungstic acid (PTA), which exhibited the excellent performance in catalyzing conversion of oleic acid (OA) for the biodiesel production. The physicochemical properties of the catalysts were characterized and analyzed using modern testing techniques and characterization methods such as XRD, FT-IR, XPS, SEM, TEM, and Hammett titration. The various influence parameters were optimized using the central composite design based the response surface methodology, where the maximum biodiesel yield of 97.0% was achieved at the MeOH/OA molar ratio of 5.9, the catalyst loading of 8%, reaction time of 6 h, and reaction temperature of 65℃. Furthermore, the stability and reusability of the prepared catalyst were also demonstrated. At last, the possible catalytic mechanism of the prepared catalyst was comprehensively described.
Sufang Chen,Yanju Qiu,Xixi Xing,Cunwen Wang,Chengchao Liu,Yuhua Zhang,Jingping Hong,Jinlin Li,Daohong Zhang 한국고분자학회 2020 Macromolecular Research Vol.28 No.3
Among the Fischer-Tropsch synthesis (FTS) catalysts, Cobalt catalysts are currently attracting a lot of research interests due to their high activity and high selectivity. But the dispersion and reducibility of cobalt catalysts with moderate interaction between cobalt and support are still a challenge. A novel amino-ended hyperbranched polyamide (AEHPA) was used to modify SBA-15 and then was applied as support for obtaining cobalt catalyst (15Co/SBA-15-N). The catalysts were characterized by XRD, TEM, XPS and H2-TPR techniques. The results showed that AEHPA doped mesoporous SBA-15 caused the generation of N species in the SBA-15 pore channels. The N-Co bonds resulted in the formation of highly-dispersed cobalt nanoparticles with uniform sizes inside the ordered mesopores of support. AEHPA doping was an effective way to modify the surface properties of the SBA-15 for immobilizing cobalt nanoparticles. Compared with the conventional 15Co/SBA-15 catalyst without doping AEHPA, the AEHPA doped 15Co/SBA-15-N catalyst showed improved cobalt dispersion and stabilized cobalt location, which led to much better reaction stability as well as C5+ selectivity.
Chenwei Li,Guoying Feng,Zhiguo Yan,Shaoping Li,Man Xu,Cunwen Wang,Yanbo Li 한국공업화학회 2022 Journal of Industrial and Engineering Chemistry Vol.116 No.-
Incorporation of nanofillers is an option to break through the trade-off of nanofiltration membranes. Inthe present work, a simultaneous synthesis method, ZIF and selective layer formed in one step, was proposedto prepare hybrid nanofiltration membrane. Co2+ ions pre-assembled on hydrolyzed polyacrylonitrile(PANH) support provided nucleation sites for ZIF-67 formation. The growth of ZIF-67 and theformation of polyethyleneimine (PEI) selective layer on the support completed in one step through codepositingof a solution of PEI and Hmim (2-methylimidazole). The feasibility of the simultaneous synthesismethod was verified by using different supports, PEIs, and the precursor concentrations. All resultsshow that ZIF-67 incorporation improved the water permenace, without significant compromising ofmembrane rejection. At an optimized condition, the obtained hybrid composite membrane showed highpermeance of 35 L/(m2*h*bar) and rejection of 93% toward PEG 200. The permeance increased by about150%–200% compared with the membrane without ZIF-67. Meanwile, the rejections of salts of the hybridmembrane were very low, exhibiting outstanding organic selectivity.