http://chineseinput.net/에서 pinyin(병음)방식으로 중국어를 변환할 수 있습니다.
변환된 중국어를 복사하여 사용하시면 됩니다.
Intramolecular [2+2] Photocycloaddition and Cycloreversion of Ferulic Acid Derivatives
Maeda, Hajime,Nishimura, Keisuke,Yokoyama, Akihiro,Sugimoto, Akira,Mizuno, Kazuhiko,Hosoda, Asao,Nomura, Eisaku,Taniguchi, Hisaji Korean Society of Photoscience 2015 Rapid communication in photoscience Vol.4 No.1
Intramolecular photocycloaddition of ferulic acid derivatives proceeded in high yields to give head-to-head intramolecular photodimers as three atropisomers. The photocycloaddition was sensitized by triplet sensitizers such as benzophenone, whereas photocycloreversion was promoted by 9,10-dicyanoanthracene (DCA) as an electron-transfer photocatalyst. On the other hand, intermolecular photocycloaddition afforded a head-to-tail photodimer.
Sueyoshi, Mitsuhiro,Furue, Toshihiko,Sato, Akihiro,Yokoyama, Kenichi,Yamadera, Yoshimi,Fujiwara, Kiyoshi,Matsuda, Katsuhiko 한국부식방식학회 2002 Corrosion Science and Technology Vol.31 No.5
Aluminum brass tubing which is highly cost-effective and has a high heat transfer property has been widely used for seawater cooled condenser in Japan. However, the tubing suffers from erosion and corrosion on the inner surface in spite of ferric-ion injection and cathodic protection. Ammonia also attacks the outer surface after long years of service. Periodic replacement with new tubing has been performed. Titanium tubing which has high corrosion resistance, has been used in new condensers and for the air removal zone of the condenser. However, its service has been restricted due to higher cost and lower elastic modulus. As a countermeasure, we have developed a high performance ferritic stainless steel tubing called "Super Stainless: FS1O" which has excellent corrosion resistance and is highly cost-effective. First, the tubings were used experimentally in our Buzen thermal power station, Unit 2 condenser in 1993, and various investigations have been performed on the extracted tubing and tube sheet every year. Ammonia attack on the outer surface, corrosion and erosion on the inner surface, crevice corrosion between the tube and the tube-sheet. Hz absorption and degradation of properties was not observed. Based on these results, 1,006 pieces of FS1O were installed in Buzen thermal power station, Unit I condenser in 1996. The tubing has been used in seawater without any corrosion problems.
( Toshiyuki Sato ),( Tetsuya Takagawa ),( Yoichi Kakuta ),( Akihiro Nishio ),( Mikio Kawai ),( Koji Kamikozuru ),( Yoko Yokoyama ),( Yuko Kita ),( Takako Miyazaki ),( Masaki Iimuro ),( Nobuyuki Hida ) 대한장연구학회 2017 Intestinal Research Vol.15 No.3
Background/Aims: Recent genome-wide analyses have provided strong evidence concerning adverse events caused by thiopurine drugs such as azathioprine (AZA) and 6-mercaptopurine. The strong associations identified between NUDT15 p.Arg139Cys and thiopurine-induced leukopenia and severe hair loss have been studied and confirmed over the last 2 years. However, other coding variants, including NUDT15 p.Val18_Val19insGlyVal, NUDT15 p.Val18Ile, and FTO p.Ala134Thr, and a noncoding variation in RUNX1 (rs2834826) remain to be examined in detail in this respect. Therefore, we investigated the correlation between these adverse events and the 5 recently identified variants mentioned above among Japanese patients with inflammatory bowel diseases (IBD). Methods: One hundred sixty thiopurine-treated patients with IBD were enrolled. Genotyping was performed using TaqMan SNP Genotyping Assays or Sanger sequencing. Results: None of the 5 variants were associated with gastrointestinal intolerance to AZA. However, NUDT15 p.Arg139Cys was significantly associated with the interval between initiation and discontinuation of AZA among patients with gastrointestinal intolerance. This variant was strongly associated with early (<8 weeks) and late (≥8 weeks) leukopenia and severe hair loss. Moreover, it correlated with the interval between initiation of thiopurine therapy and leukopenia occurrence, and average thiopurine dose. NUDT15 p.Val18_Val19insGlyVal, NUDT15 p.Val18Ile, FTO p.Ala134Thr, and RUNX1 rs2834826 exhibited no significant relationship with the adverse events examined. Conclusions: Of the 5 variants investigated, NUDT15 p.Arg139Cys had the strongest impact on thiopurineinduced leukopenia and severe hair loss; therefore, its genotyping should be prioritized over that of other variants in efforts to predict these adverse events in Japanese patients with IBD. (Intest Res 2017;15:328-337)