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아크 융해로를 이용한 β-Ti<SUB>3</SUB>O<SUB>5</SUB> 및 λ-AlxTi<SUB>3-x</SUB>O<SUB>5</SUB>의 합성
공민식(Minsik Kong),김서희(Seohee Kim),김민재(Min Jae Kim),강명준(Myeongjun Kang),지광철(Gwangcheol Ji),박성욱(Seonguk Park),이지성(Jisung Lee),손영준(Yeongjun Son),박성균(Sungkyun Park),옥종목(Jong Mok Ok) 한국물리학회 2024 새물리 Vol.74 No.1
Ti₃O<SUB>5</SUB> exhibits a metal-insulator transition (MIT) accompanied by a structural change from β- phase to λ-phase at 514 K. During the transition, Ti₃O<SUB>5</SUB> demonstrates significant resistance changes and high thermal energy storage characteristics. To harness the beneficial characteristics of Ti₃O<SUB>5</SUB>, it is essential to develop a growth method that yields homogeneous samples and to control the phase transition temperature. In this study, we successfully synthesized high-quality β-Ti₃O<SUB>5</SUB> and λ-AlxTi₃−xO5 polycrystalline samples using an arc melting method. Furthermore, the structural and physical properties of β-Ti₃O<SUB>5</SUB> and λ-AlxTi₃−xO<SUB>5</SUB> were investigated as a function of the Al doping ratio. Our results suggest that the arc melting method provides an effective way to synthesize high-quality Ti₃O<SUB>5</SUB> and control the transition temperature of the MIT.