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온실기체 (CH<sub>4</sub>, CO<sub>2</sub>, N<sub>2</sub>O)의 하구언갯벌 배출량과 배출특성연구
김득수,Kim, Deug-Soo 한국대기환경학회 2007 한국대기환경학회지 Vol.23 No.2
A closed flux chamber system was used for measuring major greenhouse gas (GHG) emission from tideland and/or wetland soils in estuarine area at Saemankum, Kunsan in southwestern Korea during from months of February to June 2006. Hourly averaged GHG soil emissions were measured two to three times a day during the ebb tide hours only. Site soils were analyzed for soil parameters (temperature, pH, total organic contents, N and C contents in soil) in the laboratory. Soil GHG fluxes were calculated based on the GHG concentration rate of change measured inside a closed chamber The analysis of GHG was conducted by using a Gas Chromatography (equipped with ECD/FID) at laboratory. Changes of daily, monthly GHGs' fluxes were examined. The relationships between the GHG emissions and soil chemical contents were also scrutinized with respect to gas production and consumption mechanism in the soil. Soil pH was pH $7.47{\pm}0.49$ in average over the experimental period. Organic matter contents in sample soil was $6.64{\pm}4.98\;g/kg$, and it shows relatively lower contents than those in agricultural soils in Kunsan area. Resulting from the soil chemistry data, soil nitrogen contents seem to affect GHG emission from the tidal land surface. The tidal soil was found to be either source or sink for the major GHG during the experimental periods. The annual average of $CH_{4}\;and\;CO_{2}$ fluxes were $0.13{\pm}0.86\;mg\;m^{-2}h^{-1}\;and\;5.83{\pm}138.73\;mg\;m^{-2}h^{-1}$, respectively, which will be as a source of these gases. However, $N_{2}O$ emission showed in negative flux, and the value was $-0.02{\pm}0.66\;mg\;m^{-2}h^{-1}$, and it implies tidal land surface act as a sink of $N_{2}O$. Over the experimental period, the absolute values of gas fluxes increased with soil temperature in general. Averages of the ambient gas concentration were $86.8{\pm}6.\;ppm$ in $CO_{2},\;1.63{\pm}0.34\;ppm\;in\;CH_{4},\;and\;0.59{\pm}0.15\;ppm\;in\;N_{2}O$, respectively. Generally, under the presence of gas emission from agricultural soils, decrease of gas emission will be observed as increase in ambient gas concentration. We, however, could not found significant correlation between the ambient concentrations and their emissions over the experimental period. There was no GHG compensation points existed in tide flat soil.
인산형 연료전지와 유기랭킨사이클 연계시스템에 대한 경제성 평가
김득수,유호선,Kim, Deug Soo,Yoo, Hoseon 한국플랜트학회 2022 플랜트 저널 Vol.18 No.1
In this study, the operational characteristics of the 7.48 MW fuel cell power plant consisting of 17 units of 440 kW Phosphoric Acid Fuel Cell (PAFC) in operation since its commercial operation in December 2017 were explained and the heat recovery process of the plat using Organic Rankine Cycle (ORC)was simulated. The fuel cell system performance improvement and economic assessment were analyzed by calculating the amount of heat recovery and electric power available when connecting a 125 kW XLT Model ORC for hot water heat sources with 105℃, 40.8 t/h. The result of the study shows that integrating the 125 kW ORC to PAFC power plant would improve generating efficiency by about 0.6% through annually 851,472 kWh of electricity produced by ORC, and fuel cell and ORC integrated systems were calculated to have a 0.35% higher Internal Return Ratio and more Net Present Value of 1,249 million KRW than not installing ORC despite installation costs.
서울 도심대기의 NO, NO<sub>2</sub>와 O<sub>3</sub> 사이의 대기화학적 특성 연구
김득수,정진상,안준영,Kim, Deug-Soo,Jeong, Jinsang,Ahn, Joonyoung 한국대기환경학회 2016 한국대기환경학회지 Vol.32 No.4
This study was conducted to understand roles of $NO_x(=NO+NO_2)$ on high $O_3$ episodes at an urban monitoring station in Seoul. Concentrations of NO, $NO_2$, $NO_y$ and $O_3$ were measured intensively at KIST monitoring station which located at urban center in Seoul metropolitan area during May 18~June 13, 2015. Sampling period was planed because high $O_3$ and PM occurred frequently during from late spring to early summer months in Seoul. The experimental site locates in NW from center of Seoul and is surrounded by residential area. Belt highway of the city runs from north to west side nearby experimental site. Vehicle exhaust emissions due to heavy traffic influenced $NO_x$ concentration at the site during northwesterly wind. Specific $NO_2$ concentration was measured by Blue Light photolytic converter, and it was compared to $NO_2$ concentration measured by molybedenum converter. $[NO_2]_{phtolysis}$ was usually lower than $[NO_2]_{molybedenum}$ during the experiment period; however their diurnal variations were very similar. The linear relationship between these $NO_2$ concentrations was found to be $[NO_2]_{phtolysis}$=0.64 $[NO_2]_{molybedenum}$ - 2.6, $r^2$=0.83 during May 16~8, 2015. The difference between $NO_2$ by molybdenum converter and by photolytic converter (${\Delta}NO_2=[NO_2]_{molybedenum}-[NO_2]_{phtolysis}$) accounted for residual $NO_y$ which can represent $NO_z$ (=$NO_y-NO_x$). $O_3$ concentration showed typical daily trend which has maximum at late afternoon and minimum during the night. $O_3$ increased at a rate of 7 ppb/hr since 8 am. and reached the maximum concentration (~80 ppb) at 3 pm.. The diurnal pattern of $O_3$ was inversely related with that of $NO_2$, suggesting that the formation of $O_3$ was the result of photochemical activity of $NO_2$.