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- 저자 : Yoga Priastomo (검색결과 2 건)
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Jumina,Ifa Amalina,Sugeng Triono,Yehezkiel Steven Kurniawan,Yoga Priastomo,Keisuke Ohto,Bohari M. Yamin 대한화학회 2021 Bulletin of the Korean Chemical Society Vol.42 No.3
At present, biodiesel remains an untapped fuel source while crude oil reserves are being depleted. Extensive efforts are necessary to achieve efficient biodiesel production, but catalytic activity in methyl palmitate production remains unsatisfactory. In this study, we report the synthesis and organocatalyst activity of C-arylcalix[4]-2-methylresorcinarene sulfonic acids for biodiesel production. The presence of a methyl group on an aromatic ring is expected to disturb the intramolecular hydrogen bonds; thus, each hydroxyl group could be utilized for the catalytic process. C-arylcalix[4]-2-methylresorcinarene sulfonic acids were prepared from cyclocondensation and sulfonation reactions yielding compounds 1?6 at rates of 66.7%?86.6%. By evaluating the organocatalytic activity of the C-arylcalix[4]-2-methylresorcinarene sulfonic acids, we found that 4?mol% of compound 5 exhibited the highest yield (97.8%) of methyl palmitate at 338?K for 6-h reaction time, which is remarkable. These findings show that C-arylcalix[4]-2-methylresorcinarene sulfonic acids are promising heterogeneous catalyst materials for biodiesel production.
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Science and Technology Progress on the Desulfurization Process of Crude Oil
Jumina,Yehezkiel Steven Kurniawan,Bambang Purwono,Dwi Siswanta,Yoga Priastomo,Agustinus Winarno,Joko Waluyo 대한화학회 2021 Bulletin of the Korean Chemical Society Vol.42 No.8
Currently, crude oil still remains an irreplaceable energy source for chemical industrial processes, transportation systems, electricity, and other human activities. However, crude oil contains sulfur elements as the major impurities in the form of aliphatic and aromatic organosulfur compounds. During the combustion of fuel, these organosulfur compounds are converted to harmful SOx gases; thus, many countries strictly limit the maximum sulfur content in the fuels. To fulfill the government regulation, refineries are trying to decrease the maximum sulfur content in crude oil through several desulfurization technologies, such as hydrodesulfurization, adsorption, oxidative-desulfurization, alkylation, and biodesulfurization. Each desulfurization technology has its own advantages and disadvantages. In this review article, we aimed to briefly summarize the progress in the developing science and technology of each desulfurization process of crude oil. Several fields in the desulfurization process are still facing challenges to create better designs and development for a safer future of the world.
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