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Catalytic reduction of nitric oxide by methane over CaO catalyst
Wei Xu,Huiling Tong,Changhe Chen,Xuchang Xu 한국화학공학회 2008 Korean Journal of Chemical Engineering Vol.25 No.1
The selective catalytic reduction of nitric oxide by methane was studied over CaO catalyst in a bubbling fluidized bed in the temperature range of 800-900 oC, in which NO cannot be reduced by CH4 without CaO catalyst. The nitric oxide conversion was found to depend on oxygen and CH4 feed concentration, and also on temperature. In addition, the presence of water vapors in the flue gas enhanced the NO reduction admirably well in the absence of O2. But water vapor has an inhibiting effect on the reaction while O2 is present in the flue gas. The addition of CO2 poisoned the CaO catalyst and exhibited a detrimental effect on NO conversion at the working temperature range, 800-900 oC. However, with a temperature rise to 900 oC the CO2 poisoning effect on NO reduction was weakened. The mechanism was studied and discussed according to the references in the paper.
Mass transfer and kinetics study on the sulfite forced oxidation with manganese ion catalyst
Zhao Bo,Li Yan,Zhuo Yuqun,Tong Huiling,Zhang Xiaowen,Chen Changhe 한국화학공학회 2007 Korean Journal of Chemical Engineering Vol.24 No.3
limestone scrubbing is the most common flue gas desulfurization process (FGD) for control of sulfurdioxide emissions from the combustion of fossil fuels. Forced oxidation, which controls the overall reaction of the sulfurdioxide absorption, is the key path of the process. Manganese which comes from the coal is one of the catalysts duringthe forced oxidation process. In the present work, the two-film theory was used to analyze the sulfite forced oxidationreaction with an image boundary recognition technique, and the oxidation rate was experimentally studied by contactingpure oxygen with a sodium sulfite solution. There was a critical sulfite concentration 0.328 mol/Lwithout catalyst ortion constant k; furthermore, we obtained the order with respect to the sulfite and Mn2+ concentrations. When the Mn2+catalyst concentration was kept unchanged, the sulfite oxidation reaction rate was controlled by dual film and the reac-tion kinetics was first order with respect to sulfite while concentration was below 0.328 mol/L; the sulfite oxidationreaction rate was controlled by gas film only and the reaction kinetics was zero order with respect to sulfite while concentration over 0.328 mol/L. When concentration was kept unchanged, the sulfite oxidation reaction rate de-pended on gas-liquid mass transfer and the reaction kinetics was diferent in various stages with respect to Mn2+ con-centrations.