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        Influence of thiourea synthesis with silica fume on the corrosion rate of reinforcement concrete

        Tawfik Taher A.,El-Yamani Magdy A.,Serag Faried A.,Mohammed Shimaa M.,AbdEl-Hafez Gh.M. 한국자원공학회 2020 Geosystem engineering Vol.23 No.3

        The examination of corrosion rate for steel reinforcement existent in concrete was carried out in the presence of silica fume and thiourea. The ordinary Portland cement (OPC) replacement was conducted with silica fume material at 5 and 10% by cement weight for concrete production, in addition to that using various percentage of thiourea (1, 2, 3 4 and 5%) added to concrete. Monitoring and estimating the corrosion rate for reinforcing steel existent in concrete with and without silica fume and thiourea was held with the usage of corrosion test cell. Besides, compressive and splitting tensile strength submerged in fresh and salty water of hardened concrete with and without silica fume and thiourea that were considered in the study. The immersion for all the samples of steel reinforcement with salty water (tap water with 1.5% of calcium sulphate and 3% of sodium chloride) for about 90 days of exposure were studied. The best results for the lowest corrosion rate were obtained when a mixture of silica fume with thiourea is used with concentrations of 10 and 3%, respectively compared with the ordinary concrete.

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        Role of expanded clay aggregate, metakaolin and silica fume on the of modified lightweight concrete properties

        Tawfik Taher A.,AlSaffar Doha M.,Tayeh Bassam A.,Metwally Khaled Ali,ElKattan Ibrahim M. 한국자원공학회 2021 Geosystem engineering Vol.24 No.3

        This investigation aimed to assess the effect of micro-cementitious materials on the mechanical properties and sulphate resistance of modified eco-efficient lightweight concrete (MDLWC). A modified lightweight concrete (MDLWC) was produced by mixing Light-expanded clay aggregate (LECA) with normal coarse aggregate (dolomite cushed rock). The impact of using different percentage of micro-cementitious materials which was micro silica fume (5–20%) and metakaolin(10–35%) on the mechanical properties (compressive strength, splitting tensile and flexural strength), waves transmission velocity of the ultrasonic pulses and sulphate resistivity of MDLWC was studied. The overall results illustrated that the use of micro-cementitious materials in MDLWC caused an enhancement on MDLWC properties. However, the MDLWC specimens containing micro silica fume showed better results than metakaolin. The best results were observed while using samples containing 10% micro silica fume and 30 % metakaolin individually or combined. In addition, the usage of combined mixture of 10% micro silica fume and 30% metakaolin MDLWC mix showed the best improvement rate in compressive, splitting tensile and flexural strengths by 25, 53.3 and 66.6%, respectively, compared to control MDLWC specimens. On the other hand, the direct empirical equations were proposed on the basis of strong and nonlinear regression analysis using the test data to predict the mechanical properties of MDLWC relationships, rationally. Experimental tests were conducted on ultrasonic pulses velocity, which showed good correlation equation strength of MDLWC. Scanning electron microscopy illustrated that the pores of concrete is smaller for SF and MK individually or combined with MDLWC compared to the control concrete, demonstrating an enhancement within the interfacial microstructure with the pozzolanas incorporation. The previous difference could be explained due to the concrete strength and sulphate penetrability to an extent.

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