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Sapchenko, Sergey A.,Samsonenko, Denis G.,Dybtsev, Danil N.,Melgunov, Maxim S.,Fedin, Vladimir P. Royal Society of Chemistry 2011 Dalton transactions Vol.40 No.10
<P>Zn(<SMALL>II</SMALL>)-containing metal–organic framework (MOF) [Zn<SUB>4</SUB>(dmf)(ur)<SUB>2</SUB>(ndc)<SUB>4</SUB>] (ndc<SUP>2−</SUP> = 2,6-naphtalenedicarboxylate, ur = urotropin, dmf = N,N′-dimethylformamide) was synthesized and characterized by X-ray crystallography and gas sorption analysis. Host MOF retains its crystallinity after guest removal and exchange. Single-crystal to single-crystal formation of different host–guest systems with benzene and ferrocene was investigated. Interesting guest-depended luminescence properties of the porous host framework were observed.</P> <P>Graphic Abstract</P><P>A Zn(<SMALL>II</SMALL>)-containing MOF was synthesized and characterized by X-ray crystallography and gas sorption analysis. <IMG SRC='http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=c0dt00999g'> </P>