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Lata Verma,Jiwan Singh 대한환경공학회 2023 Environmental Engineering Research Vol.28 No.3
The present study deals with the utilization of waste biomass of Tectona plant refuse to synthesize the monometallic and bimetallic biochar and to examine their performance for As(III) removal from aqueous solution as well as from groundwater. The biochar materials were characterized using Scanning Electron Microscope (SEM), Fourier Transform Infrared Spectroscopy (FTIR), X-ray Diffraction (XRD), Particle Size Analysis (PSA), zeta potential and pHZPC. The enhanced removal of As(III) was observed with Fe/Mn-TB (bimetallic) which was greater than Fe-TB (monometallic) biochar. The highest adsorption was 90.35 % and 84.85 % achieved with Fe/Mn-TB and Fe-TB, respectively, at 0.5 mg/L As initial concentration 0.5 mg/L. The adsorption capacity was found to be 0.91 mg/g and 1.89 mg/g, respectively, by Fe-TB and Fe/Mn-TB. The adsorption process of As(III) has good compliance with pseudo-second order kinetics as well as Freundlich isotherm model. As(III) was adsorbed by the Fe-TB and Fe/Mn-TB possibly by electrostatic attraction, H-bond formation and complexation mechanism. Both these materials successfully removed As(III) from aqueous solution as well as from groundwater thus it can be used for the eradication of As(III) from the affected areas by utilizing them as an adsorbent in continuous flow system.
Zeenat Arif,Naresh Kumar Sethy,Lata Kumari,Pradeep Kumar Mishra,Bhawna Verma 한국화학공학회 2019 Korean Journal of Chemical Engineering Vol.36 No.7
Polyvinylidene fluoride (PVDF)/TiO2 composite ultrafiltration membranes were fabricated using different loadings of TiO2 NPs synthesized by the green route using an extract of Cajanus cajan. XRD analysis confirmed the synthesis of TiO2 nanoparticles of size 10 nm using Debye Scherrer’s equation. High hydrophobicity of PVDF restricts its successful application due to fouling in the membrane. Therefore, composite membranes were prepared via the phase inversion route and characterized by contact angle and permeation tests. The BSA filtration experiments revealed that membrane with 0.5 wt% of TiO2 exhibits excellent hydrophilicity, permeation flux, high rejection ratio, and good antifouling performance. It was observed that the fouling characteristic of the membrane is governed by the surface roughness of the membrane, and with increasing loading of TiO2 the surface roughness decreases indirectly enhancing the antifouling property of membranes. The adsorption capacity of bovine serum albumin on the membrane surface decreased from 2.85 to 2.15mg cm2 as the TiO2 loading increased from 0 to 0.02 g TiO2/g PVDF. Fouling was found due to cake formation in ultrafiltration and can be explained by Hermia’s fouling model suggesting that the solutes are not deposited into the pores, which indicates that the fouling process is physically reversible.