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A Neutral Naphthalene Diimide [2]Rotaxane
Jacquot de Rouville, Henri-Pierre,Iehl, Julien,Bruns, Carson J.,McGrier, Psaras L.,Frasconi, Marco,Sarjeant, Amy A.,Stoddart, J. Fraser American Chemical Society 2012 ORGANIC LETTERS Vol.14 No.20
<P>A neutral donor–acceptor [2]rotaxane, which has been synthesized using click chemistry, has had its solid-state structure and superstructure elucidated by X-ray crystallography. Both dynamic <SUP>1</SUP>H NMR spectroscopy and electrochemical investigations have been employed in an attempt to shed light on both geometrical reorganization and redox-switching processes that are occurring or can be induced within the [2]rotaxane.</P><P><B>Graphic Abstract</B> <IMG SRC='http://pubs.acs.org/appl/literatum/publisher/achs/journals/content/orlef7/2012/orlef7.2012.14.issue-20/ol3022963/production/images/medium/ol-2012-022963_0006.gif'></P><P><A href='http://pubs.acs.org/doi/suppl/10.1021/ol3022963'>ACS Electronic Supporting Info</A></P>