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        Proton-Conducting Polymers Derived from Radiation Grafting and Sulphonation of Poly(tetraflouroethylene-perflourovinyl ether) Film with Three Rare-Earth Elements

        Mohamed Mohamady Ghobashy,Ahmed M. Elbarbary,Naeem M. El-Sawy,Hany M. Hosni 한국고분자학회 2017 Macromolecular Research Vol.25 No.9

        Progress in the area of proton conducting polymer electrolyte membranes is closely with the enhancing of polymer electrolyte membrane fuel cells. Fluorinated polymers, e.g. poly(tetraflouroethylene-perflourovinyl ether) (PFA) film is largely driven by their thermal properties. In this article PFA film was developments to be suitable as proton conducting polymer electrolyte membranes. The grafting of acrylic acid (80%) onto the PFA film achieved by irradiation techniques and PFA-COOH was obtained. In addition, to synthesis of completely a new protonconducting sulfonated polymer ionomers this could be acheived by sequences of chemical modification steps. PFA-COOH has been anilination and sulfonated to a sufficient ionomers formation and complexion with the three rare-earth elements (Li, Cs, and Sr). After that the obtained PFA-CO-NH-ph-SO3M contains a sufficient equilibrium concentration of protons in a wet atmosphere to show useful proton conduction at ambient temperatures. The sulfonated polymers containing 63mol% sulfonic acid, and characterized by FTIR-ATR and SEM The results show that PFACO- NH-ph-SO3M wet film showed a high proton-conductivity in water (10-3 Scm-1) rather than methanol (10-6 Scm-1) in order Li+> Sr++>Cs+. This approach has interesting potential for smart thin film materials and offers also the possibility to be used in sensors and fuel cells provided that the electrolyte film thickness is in the micrometre range.

      • Evaluation of BreastLight as a Tool for Early Detection of Breast Lesions among Females Attending National Cancer Institute, Cairo University

        Labib, Nargis Albert,Ghobashi, Maha Mohamed,Moneer, Manar Mohamed,Helal, Maha Hesien,Abdalgaleel, Shaimaa Abdalaleem Asian Pacific Journal of Cancer Prevention 2013 Asian Pacific journal of cancer prevention Vol.14 No.8

        Background: Breast illumination was suggested as a simple method for breast cancer screening. BreastLight is a simple apparatus for this purpose. Objective: To evaluate the diagnostic performance of BreastLight as a screening tool of breast cancer in comparison to mammography and histopathology. Materials and Methods: This hospital-based cross sectional study was conducted in the mammography unit of the radiodiagnosis department at National Cancer Institute, Cairo University. All participants were subjected to breast examination with the BreastLight tool, mammography and ultrasonography. Suspicious cases were biopsied for histopathological examination which is considered as a gold standard. Results: The mean age of the participants was $46.3{\pm}12.4$ years. Breast illumination method had sensitivity, specificity, positive predictive value, negative predictive value and total accuracy of 93.0%, 73.7%, 91.4%, 77.8% and 88.2%, respectively in detection of breast cancer. Conclusions: Breast illumination method with BreastLight apparatus is a promising easy-to-use tool to screen for breast cancer suitable for primary health care physician or at-home use. It needs further evaluation especially in asymptomatic women.

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