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DI DI,PEITAO DONG,XUEZHONG WU,CHAOGUANG WANG,JIAN CHEN,HAOXU WANG,SHENGYI LI,JUNFENG WANG 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2014 NANO Vol.9 No.4
High-ordered particle-in-bowl (PIB) arrays are developed in this paper for surface enhancedRaman spectroscopy (SERS). A heterogeneous shadow mask, composing of the chrome (Cr) layerand colloid residues, is used to fabricate the silicon (Si) template from where the PIB arrays¯nally lift-o®. The ¯nite di®erence time domain (FDTD) method is employed to investigate theRaman enhancement mechanism of this PIB architecture. The electromagnetic (EM) ¯eld tendsto concentrate in the gap between the bowl and the particle forming the \hot spots". Theenhancement factor (EF) of the EM ¯eld is about 70 with an excitation wavelength of 785 nm. The Raman measurements validate the EM calculation of the PIB arrays. The EF is about1 : 12 ? 10 7 using Rodamine 6G (R6G) as probe molecule. The proposed PIB array is high-orderedin morphology and ultra-sensitive in Raman measurement, providing an ideal substrate forSERS-based bio-chemical sensing, disease diagnosis and analytical chemistry.
Jian Chen,Peitao Dong,Chaoguang Wang,Chenyu Zhang,Junfeng Wang,Xuezhong Wu 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2017 NANO Vol.12 No.11
A simple method for improving surface-enhanced Raman scattering (SERS) performance of aligned silver nanorod (Ag NR) array was investigated. This method was to construct a kind of hybrid substrate by grafting Au@Ag core–shell nanoparticles (NPs) into Ag NR array using poly(2-vinylphridine) (P2VPy) as a bridging agent. The hybrid substrate yielded excellent SERS performance as its detection limit improved from 10 -6 M to 10 -8 M using trans-1,2-bis(4-pyridyl)ethylene (BPE) as probe molecule, which was increased by two orders of magnitude compared with Ag NR array substrate. The significant improvement of SERS performance of Ag NR arrays was attributed to the addition of Au@Ag core–shell NPs. As a result of surface plasmon resonance generated by the interaction of electromagnetic (EM) (IAEM) filed between NP and NR structures, increasing hotspots were found at the connections of NPs and NRs, the gaps of adjacent rods, and the gaps of two particles consequently. These results were validated by the finite difference time domain (FDTD) calculation. Besides, hybrid substrate shows good performance in stability and reproducibility. The proposed method was simple and robust, which promoted SERS performance of Ag NR array effectively, showing great potential in the application of SERS substrate fabrication and SERS-based bio-chemical sensing.