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Polyacryloyl Chloride 로부터 고분자 염료의 합성
이상원,엄달호,안태완 崇田大學校 1982 論文集 Vol.12 No.1
Several polymeric azo dyes were synthesized from reactive polymer, polyacryloyl chloride. The monomer, acryloyl chloride was synthesized, and then polymerized in N, N-dimethylformamide. Polyacryloyl chloride was reacted with 1, 4-phenylenediamine to poly-N-(4-aminophenyl) acrylamide, and the resulting polymer was investigated by infrared spectroscopy, nuclear magnetic resonance spectroscopy, and elemental analysis. The polymeric azo dyes were obtained by diazotization and coupling reaction of free amine group of the intermediate polymer. The polymeric dyes were insoluble in water and general organic solvents. The colors of these dyes were determined by visible spectrophotometry.